Zinc(II) and manganese(II) coordination polymers constructed by 2-naphthyl imidazole dicarboxylate: syntheses,structures and properties |
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| Authors: | Shaofeng Liu Beibei Wang Mengwei Guo |
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| Affiliation: | College of Chemistry and Molecular Engineering, Zhengzhou University, Zhengzhou, Henan 450001, P.R. China |
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| Abstract: | Three coordination polymers [Zn(μ3-HNIDC)(CH3OH)]n (H3NIDC = 2-(2-naphthyl)-1H-imidazole-4,5-dicarboxylic acid) (1), [Mn(μ2-HNIDC)(4,4′-bipy)]n (4,4′-bipy = 4,4′-bipyridine) (2) and [Mn2(μ2-HNIDC)2(phen)2]n (phen = 1,10-phenanthroline) (3) have been solvothermally synthesised and structurally characterised by single-crystal X-ray diffraction, elemental analyses, thermal analyses and IR spectra. Polymer 1 displays a three-dimensional open architecture with one-dimensional (1D) channels. Polymer 2 exhibits a sheet structure containing infinite rectangles. Polymer 3 presents a 1D wave chain structure. The solid-state photoluminescence of 1 has been investigated as well. |
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| Keywords: | coordination polymer imidazole dicarboxylate crystal structure property |
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