Supramolecular inclusion of a pillared double-layered host by an anion-directed second-sphere coordination |
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Authors: | Fang Guo Fang Xia Na Lu Jian Tong Wen-sheng Guo |
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Institution: | 1. College of Chemistry, Liaoning University , Shenyang, 110036, P.R. China fguo@lnu.edu.cn;3. College of Chemistry, Liaoning University , Shenyang, 110036, P.R. China |
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Abstract: | In this paper, we have illustrated the utilisation of a second-sphere coordination approach to construct supramolecular inclusion solids with varieties of guest molecules. A flexible molecule N,N,N′,N′-tetra-p-methylbenzyl-ethylenediamine (L1) bearing doubly protonated H-bond donors was designed, capable of forming N–H…Cl hydrogen bonds with a crystallographically unique chloride anion, to construct an anion-directed ligand. The pillared double-layered host framework was constructed by an anion-directed ligand and primary coordination sphere CoCl4]2 ? through weak C–H…Cl hydrogen-bonding interactions. A variety of guest molecules, such as p-anisaldehyde, 1,4-dimethoxy-2,5-bis(methoxymethyl)benzene, can be included, leading to the formation of novel supramolecular inclusion solids: L1]·4H]+·CoCl4]2 ? ·2Cl? ·1.5C8H8O2]·0.25CH3OH] (1) and L1]·4H]+·CoCl4]2 ? ·2Cl? ·1.5C12H20O4]·0.5CH3OH] (2). We have presented herein the utilisation of a second-sphere coordination approach to construct supramolecular inclusion solids with a variety of guest molecules. A novel type of a pillared double-layered host framework was constructed by a second-sphere coordination between the anion-directed ligand (L1 = N,N,N′,N′-tetra-p-methylbenzyl-ethylenediamine) and CoCl4]2 ? through weak C–H…Cl hydrogen-bonding interaction, and a variety of guest molecules, such as p-anisaldehyde, 1,4-dimethoxy-2,5-bis(methoxymethyl)benzene, can be included, leading to the formation of supramolecular inclusion solids: L1]·4H]+·CoCl4]2 ? ·2Cl? ·1.5C8H8O2]·0.25CH3OH] (1) and L1]·4H]+·CoCl4]2 ? ·2Cl? ·1.5C12H20O4]·0.5CH3OH] (2) |
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Keywords: | second-sphere coordination anion receptor inclusion complex pillared double-layered host [CoCl4]2 ? |
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