Crystal structure of a Mn(II) complex with isatin-hydrazone-S-benzyldithiocarbazate |
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| Authors: | J -J Xia |
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| Institution: | 1. School of Materials and Chemical Engineering Anhui University of Architecture, Hefei, P. R. China
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| Abstract: | The reaction of Mn(OAc)2·4H2O with isatin-hydrazone-S-benzyldithiocarbazate (HIsa-SBn) results in the formation of a bis-ligand complex Mn(Isa-SBn)2]·2DMF. Its single crystal is obtained and the structure is determined by X-ray diffraction. It belongs to a monoclinic space group C2/c with the cell parameters: a = 23.290(4) Å, b = 11.4980(18) Å, c = 18.483(5) Å, V = 4087.6(14) Å3. The Mn(II) atom is six-coordinated with two amide O atoms, two azomethine N atoms, and two thiolate S atoms, resulting in a distorted octahedral geometry. |
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