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Thermodynamic properties of the intermediate phases of the Ag-Sb-Se system
Authors:M. V. Moroz  M. V. Prokhorenko
Affiliation:1. National University of Water Management and Nature Resources Use, Rivne, 33000, Ukraine
2. Lviv Polytechnic National University, Lviv, 79000, Ukraine
Abstract:The emf (?) dependence of C|Ag|AgI|glass Ag2GeS3|D|C galvanic elements on temperature is studied in the range of 470 to 575 K (C represents current electrodes, D denotes equilibrium three-phase alloys of individual Ag-Sb-Se systems, and AgI|glass Ag2GeS3 is a bilayer membrane with purely ionic (Ag+) electroconductivity). Analytical equations ? = ?(T) are used to calculate the thermodynamic functions of saturated solid solutions of the AgSbSe2, Sb2Se3, and Ag2Se phases of the Ag-Sb-Se system in the standard state.
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