| A New Complex [Ni（L）2]·2H2O Containing an Interesting Six-membered Water Ring （HL = 2-Iminomethyl-6-methoxy-phenol） |
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| 作者姓名： | ZHANG Shu-Hua ;ZENG Ming-Hua ;LIANG Hong |
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| 作者单位： | State Key Laboratory of Coordination Chemistry Nanjing University，State Key Laboratory of Coordination Chemistry Nanjing University，State Key Laboratory of Coordination Chemistry Nanjing University，Nanjing 210093 China Key Laboratory of Non-ferrous Metal Materials and Processing Technology (Guilin University of Technology) Ministry of Education Guilin 541004 China，Nanjing 210093 China，Nanjing 210093 China |
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| 基金项目： | Supportod by the Key Laboratory of Non-ferrous Metal Materials and New Processing Technology, Ministry of Education and the State Key Laboratory of Coordination Chemistry |
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| 摘 要： | A new complex, Ni（L）2]·2（H2O） I （HL = 2-iminomethyl-6-methoxyphenol）, has been synthesized and structurally determined. The crystal belongs to the trigonal system, space group R3- with a = 1.9341 （3）, b = 1.9341 （3）, C = 1.2048（2） nm, V = 3.9029（11） nm^3, Mr = 395.05, Z = 9, Dc = 1.513 g·cm^-3, F（000） = 1854,μ= 1.153 mm^-1 and S = 1.014. Each Ni^Ⅱ atom is four-coordinated by two N and two O atoms from two different L anions to give a slightly distorted square-plane geometry. The complex forms a 3-D network structure through N-H...O and O-H...O hydrogen bonds containing an interesting six-membered water ring.
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| 关 键 词： | 六水环状物 2-亚氨基甲基-6-甲氧基苯酚 结构分析 镍配位化合物 |
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