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Tailoring crystal polymorphs of organic semiconductors towards high-performance field-effect transistors
Authors:Yong-Gang Zhen  Huan-Li Dong  Lang Jiang  Wen-Ping Hu
Affiliation:a Beijing National Laboratory for Molecular Sciences, Key Laboratory of Organic Solids, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China;b Tianjin Key Laboratory of Molecular Optoelectronic Sciences, Department of Chemistry, School of Sciences, Tianjin University & Collaborative Innovation Center of Chemical Science and Engineering(Tianjin), Tianjin 300072, China
Abstract:As a quite ubiquitous phenomenon, crystal polymorph is one of the key issues in the field of organic semiconductors. This review gives a brief summary to the advances on polymorph control of thin film and single crystal of representative organic semiconductors towards high-performance field-effect transistors. Particularly, the relationship between crystal polymporh and charge transport behaviour has been discussed to shed light on the rational preparation of outstanding organic semiconducting materials with desired crystal polymorph.
Keywords:Organic semiconductors  Crystal polymorphs  Crystal engineering  Charge transport  Field-effect transistors  
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