A supramolecular bottlebrush polymer assembled on the basis of cucurbit[8]uril-encapsulation-enhanced donor-acceptor interaction |
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| Authors: | Zhi-Jian Yin Zong-Quan Wu Feng Lin Qiao-Yan Qi Xiao-Na Xu Xin Zhao |
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| Institution: | a Department of Polymer Science and Engineering, School of Chemistry and Chemical Engineering, Hefei University of Technology, Hefei 230009, China;
b Key Laboratory of Synthetic and Self-assembly Chemistry for Organic Functional Molecules, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032, China |
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| Abstract: | A supramolecular bottlebrush polymer has been constructed in water through the self-assembly of a rigid electron-deficient building block and an electron-rich monomer which bears two tetraethylene glycol chains, driven by CB8]-encapsulation-enhanced donor-acceptor interaction. The as-formed supramolecular bottlebrush polymer has been characterized by 1H NMR titration experiment, UV-vis spectroscopy, DLS and 2D 1H NMR DOSY. |
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| Keywords: | Self-assembly Supramolecular polymer Cucurbit[8]uril Donor-acceptor interaction Bottlebrush polymer |
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