Nitridation: A simple way to improve the catalytic performance of hierarchical porous ZSM-5 in benzene alkylation with methanol |
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Authors: | Jing-Hui Lyu Hua-Lei Hu Jia-Yao Rui Qun-Feng Zhang Jie Cen Wen-Wen Han Qing-Tao Wang Xiao-Kun Chen Zhi-Yan Pan Xiao-Nian Li |
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Affiliation: | a Industrial Catalysis Institute of Zhejiang University of Technology, State Key Laboratory Breeding Base of Green Chemistry Synthesis Technology, Hangzhou 310032, China;b Department of Environmental Engineering, Zhejiang University of Technology, Hangzhou 310032, China |
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Abstract: | Nitrided hierarchical porous ZSM-5 was synthesized by nitridation of hierarchical porous ZSM-5 with flowing ammonia at elevated temperature. The samples were characterized by XRD, SEM, Nitrogen sorption isotherms, NH3-TPD and Py-IR, and evaluated in alkylation of benzene and methanol. The result indicated that the high specific surface area of parent ZSM-5 was maintained, while the Brönsted acidity was effectively adjusted by nitridation. Moreover, the high suppression of ethylbenzene was observed on nitrided catalyst and this could be attributed to the decrease of Brönsted acidity which suppressed the methanol to olefins reactions. |
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Keywords: | Nitridation Hierarchical porous ZSM-5 Benzene alkylation with methanol Ethylbenzene |
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