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Porous Si/C composite as anode materials for high-performance rechargeable lithium-ion battery
Authors:Bingbing Deng  Lian Shen  Yangai Liu  Tao Yang  Manshu Zhang  Renjie Liu  Zhaohui Huang  Minghao Fang  Xiaowen Wu
Institution:a Beijing Key Laboratory of Materials Utilization of Nonmetallic Minerals and Solid Wastes, National Laboratory of Mineral Materials, School of Materials Science and Technology, China University of Geosciences, Beijing 100083, China; b College of Materials and Environmental Engineering, Hangzhou Dianzi University, Hangzhou 310036, China
Abstract:A novel porous silicon was synthesized through a magnesiothermic reduction method of molecular sieve for the first time, Si/C composite was synthesized by using pitch as carbon source. The porous Si/C composite shows a high initial specific capacity of 2018.5 mAh/g with current density of 0.1 A/g. When the current density increases to 2 A/g, it still exhibits high average specific capacity of 640.3 mAh/g. The porous structure can remit the Si particle pulverization during the lithiation/delithiation process. This article can provide a reference for the research of the porous Si anode for the high performance rechargeable lithium-ion battery.
Keywords:Magnesiothermic reduction  Porous Si  Lithium-ion battery  Anode materials  Carbon coating  
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