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Biomass derived nitrogen doped carbon with porous architecture as efficient electrode materials for supercapacitors
Authors:Cuijuan Xuan  Zongkai Peng  Jie Wang  Wen Lei  Kedong Xia  Zexing Wu  Weiping Xiao  Deli Wang
Affiliation:Key Laboratory of Material Chemistry for Energy Conversion and Storage(Huazhong University of Science and Technology), Ministry of Education, Hubei Key Laboratory of Material Chemistry and Service Failure, School of Chemistry and Chemical Engineering, Huazhong University of Science and Technology, Wuhan 430074, China
Abstract:Developing porous carbon materials with low-cost, sustainable and eco-friendly natural resources is emerging as an ever important research field in the application of high-performance supercapacitor. In this paper, a simple synthetic method to fabricate nitrogen doped porous carbon (NPC) is developed via a one-pot carbonization of sodium alginate and urea. The as-prepared NPC annealed at 700℃ with mesoand macro-porous structure exhibits excellent specific capacitance (180.2 F/g at 1 A/g) and superior cycling life when serves as electrode materials for supercapacitor. Moreover, the investigation on the annealing temperature demonstrates that NPC pyrolysis at 700℃ possesses relatively high pyrrole nitrogen and pyridine nitrogen, which is favorable for enhancing supercapacitor performance. This work extends biomass derived carbon materials in energy storage applications.
Keywords:Supercapacitor  Porous carbon  N-doping  Biomass  Sodium alginate  
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