Direct synthesis of nitriles by Cu/DMEDA/TEMPO-catalyzed aerobic oxidation of primary amines with air |
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| Authors: | Xian-Tao Ma Hao Xu Ying-Lin Xiao Chen-Liang Su Jian-Ping Liu Qing Xu |
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| Institution: | a SZU-NUS Collaborative Innovation Center for Optoelectronic Science & Technology, Key Laboratory of Optoelectronic Devices and Systems of Ministry of Education and Guangdong Province, College of Optoelectronic Engineering, Shenzhen University, Shenzhen 518060, China;
b College of Chemistry and Materials Engineering Department, Wenzhou University, Wenzhou 325035, China |
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| Abstract: | By screening the copper catalysts, ligands, and the reaction conditions, a simple CuCl/DMEDA/TEMPO catalyst system readily available from commercial sources is developed for a direct and selective synthesis of the useful nitriles by an aerobic oxidation reaction of primary amines using air as an advantageous oxidant under mild conditions. |
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| Keywords: | Aerobic oxidation Air Amines Copper catalysis Nitriles |
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