Supported ionic liquids: ordered mesoporous silicas containing covalently linked ionic species |
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Authors: | Gadenne Benoît Hesemann Peter Moreau Joël J E |
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Affiliation: | UMR5076, Heterochimie Moleculaire et Macromoleculaire, 8 rue de l'Ecole Normale, 34296 Montpellier Cedex 05, France. |
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Abstract: | Ordered mesoporous silicas with hexagonal or lamellar architectures incorporating covalently bound ionic species were synthesized via a template directed hydrolysis-polycondensation of tetraethoxysilane (TEOS) with triethoxysilylated imidazole [(EtO)(3)Si(CH(2))(3)-Im] or alkylimidazolium halides [(EtO)(3)Si(CH(2))(3)-Im(+)-R Hal(-)]. |
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