Oxomolybdenum(V) complexes of 2-benzothiazolyl hydrazones |
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| Authors: | Sharada R Girish Vidyanand K Revankar Vinayak B Mahale |
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| Institution: | (1) Department of Chemistry, Karnatak University, 580 003 Dharwad, India |
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| Abstract: | Summary Oxomolybdenum(V) complexes of general formulae Mo2O3L2Cl2]H2O and Mo2O3L2(OH)2(H2O)2] (LH = hydrazones derived from 2-hydrazinobenzothiazole with salicyladehyde, 5-methyl-, 5-chloro-, 5-bromo-, 3-methoxysalicyldehyde
and 2-hydroxy-1-naphthaldehyde) have been prepared and characterized by elemental analysis, conductivities, magnetic moments,
thermal studies, and i.r., u.v.-vis. and e.p.r. spectra. The data suggest that the complexes are non-electrolytes, paramagnetic
and have distorted octahedral structures with possible metal-metal interactions via oxo bridging. |
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