微波吸收法研究Mn,Cu掺杂对ZnS:Mn,Cu光生载流子复合过程的影响

采用微波吸收法，测量了ZnS:Mn,Cu粉末材料受到超短脉冲激光激发后，其光生电子和浅束缚态电子的衰减过程.发现Mn,Cu的浓度对导带电子的寿命有明显的影响，提高掺杂浓度会使光生电子的寿命大大缩短，还研究了掺杂浓度对光致发光强度的影响. 关键词： 发光材料 硫化锌 光电子 微波吸收技术

Investigation of influences of concentration of Mn and Cu dopants on the decay process of photogenerated charge carriers in the ZnS:Mn,Cu luminescence materials

The decay process of photogenerated charge carriers of ZnS:Mn,Cu luminescence materials after excitation with a short-pulse laser has been investingated in this paper by using the microwave absorption dielectric spectrum detection technique. It was found that the concentration of the Cu and Mn dopants has a great influence on the lifetime of electrons in the conduction band. The lifetime of electrons in the conduction band decreases obviously with increasing concentration of the Cu and Mn dopants. The effect of the concentration of Cu and Mn dopants on the luminescence intensity was also investigated.