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Toward the synthesis of the antibiotic branimycin: novel approaches to highly substituted cis-decalin systems |
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| Authors: | Mulzer Johann Castagnolo Daniele Felzmann Wolfgang Marchart Stefan Pilger Christian Enev Valentin S |
| Institution: | Institut für Organische Chemie, Universit?t Wien, W?hringer Strasse 38, 1090 Wien, Austria. johann.mulzer@univie.ac.at |
| Abstract: | A variety of highly functionalized cis-decalin systems have been prepared by means of the stereoselective transannular Diels-Alder (TADA) reaction of a (Z,E,Z,Z)-tetraene macrolide, and by means of intramolecular nitrile oxide olefin (INOC) or ring-closing metathesis (RCM) annulations to quinic acid derivatives. |
| Keywords: | annulation Diels–Alder reaction ring‐closing metathesis stereoselective synthesis synthesis design |
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