| Abstract: | Two new inorganic‐organic complexes, namely, Ag2(hmt)2]Cr2O7·H2O ( 1 ) and Ag(hmt)(tar)0.5]·H2O ( 2 ), (hmt = hexamethylenetetramine, Tar = tartarate,), have been synthesized in H2O/CH3CN solvent at room temperature. Both molecules have the common Ag3hmt3]3+ layers. Compound 1 is a two‐dimensional structure, and Complex 2 shows three‐dimensional topology. In complex 2 , the tartarate molecules are connected with adjacent layers to form parallelogram pores of 18.55×7.44 Å, which are occupied by two water molecules. (© 2004 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim) |
