Excess molar volumes for ternary mixture (N,N-dimethylformamide+1-propanol+water) at the temperature 298.15 K |
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Institution: | 1. Thin Film and Nanotechnology Laboratory, Department of Physics, Dr. Babasaheb Ambedkar Marathwada University, Aurangabad-431004, Maharashtra, India;2. Department of Nanotechnology, Dr. Babasaheb Ambedkar Marathwada University, Aurangabad-431004, Maharashtra, India;1. Department of Physics, Ghatal Rabindra Satabarsiki Mahavidyalaya, Ghatal-721212, Paschim Medinipur, West Bengal, India;2. UGC-DAE Consortium for Scientific Research, Kolkata Centre, III/LB-8, Bidhannagar, Kolkata 700098, India;1. Thin Film and Nanotechnology Laboratory, Department of Physics, Dr. Babasaheb Ambedkar Marathwada University, Aurangabad 431004, MS, India;2. Department of Nanotechnology, Dr. Babasaheb Ambedkar Marathwada University, Aurangabad 431004, MS, India;3. SRM University, SRM Nagar, Kancheepuram District, Kattankulathur, Tamil Nadu 603 203, India;4. UGC DAE Consortium for Scientific Research, Indore 452001, MP, India;1. Pappas Center for Neuro-Oncology, Massachusetts General Hospital Cancer Center, Harvard Medical School, 32 Fruit Street, Boston, MA 02114, United States;2. Department of Neurosurgery, Massachusetts General Hospital, Harvard Medical School, 55 Fruit Street, White 502, Boston, MA 02114, United States;3. Department of Surgery, Brigham & Women’s Hospital, Harvard Medical School, 75 Francis Street – CA034, Boston, MA 02115, United States |
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Abstract: | The results of excess molar volumes for ternary mixture N,N-dimethylformamide (DMF)+1-propanol+water and for binary constituents, DMF+water, DMF+1-propanol and 1-propanol+water at 298.15 K are reported. Several empirical expressions were used to predict and correlate the ternary excess molar volumes from experimental results on the constituent binaries. A pseudo-binary mixture approach (PBMA) was used to analyze the system studied. The partial molar volumes of 1-propanol at infinite dilution in fmDMF+(1−fm)water] mixed solvents at their several fixed composition fm were evaluated and correlated with the composition fm. |
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