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A Novel White Light Emitting Long-lasting Phosphor
引用本文:BingFuLEI YingLiangLIU ZeRenYE ChunShanSHI. A Novel White Light Emitting Long-lasting Phosphor[J]. 中国化学快报, 2004, 15(3): 335-338
作者姓名:BingFuLEI YingLiangLIU ZeRenYE ChunShanSHI
作者单位:[1]tDepartmentofChemistry,JinanUniversity,Guangzhou510632 [2]KeyLaboratoryofRareEarthChemistryandPhysics,ChangchunInstituteofAppliedChemistry,ChineseAcademyofSciences,Changchun130022
摘    要:A novel white light emitting long-lasting phosphor Cd1-xDyxSiO3 is reported in this letterThe Dy^3 doped CdSiO3 phosphor emits white light. The phosphorescence can be seen with the naked eye in the dark clearly even after the 254nm UV irradiation have been removed for about 30min. In the emission spectrum of 5% Dy^3 doped CdSiO3 phosphor, there are two emission peaks of Dy^3 , 580nm (^4F9/2→^6H13/2) and 486nm (^4F9/2→^6H15/2), as well as a broad band emission located at about 410nm. All the three emissions form a white light with CIE chromaticity coordinates x=0.3874, y=0.3760 and the color temperature is 4000 K under 254 nm excitation. It indicated that this phosphor is a promising new luminescent material for practice application.

关 键 词:硅酸镉 白光 磷光体 镝离子

A Novel White Light Emitting Long-lasting Phosphor
Bing Fu LEI,,Ying Liang LIU,Ze Ren YE,Chun Shan SHI. A Novel White Light Emitting Long-lasting Phosphor[J]. Chinese Chemical Letters, 2004, 15(3): 335-338
Authors:Bing Fu LEI    Ying Liang LIU  Ze Ren YE  Chun Shan SHI
Affiliation:Bing Fu LEI1,2,Ying Liang LIU1,Ze Ren YE2,Chun Shan SHI2 * 1Department of Chemistry,Jinan University,Guangzhou 510632 2Key Laboratory of Rare Earth Chemistry and Physics,Changchun Institute of Applied Chemistry,Chinese Academy of Sciences,Changchun 130022
Abstract:A novel white light emitting long-lasting phosphor Cd1-xDyxSiO3 is reported in this letter. The Dy3+ doped CdSiO3 phosphor emits white light. The phosphorescence can be seen with the naked eye in the dark clearly even after the 254 nm UV irradiation have been removed for about 30 min. In the emission spectrum of 5% Dy3+ doped CdSiO3 phosphor, there are two emission peaks of Dy3+, 580 nm (4F9/26H13/2) and 486 nm (4F9/26H15/2), as well as a broad band emission located at about 410 nm. All the three emissions form a white light with CIE chromaticity coordinates x=0.3874, y=0.3760 and the color temperature is 4000 K under 254 nm excitation. It indicated that this phosphor is a promising new luminescent material for practice application.
Keywords:Cadmium metasilicate   white light   long-lasting phosphor   dysprosium ion.
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