| 烯丙位氧化的几种方法 |
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| 引用本文： | 李春,司伊康.烯丙位氧化的几种方法[J].有机化学,2003,23(6):518-525. |
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| 作者姓名： | 李春 司伊康 |
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| 作者单位： | 中国医学科学院,中国协和医科大学药物研究所,北京100050 |
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| 摘 要： | 综述了近年来烯丙位氧化的研究进展，详细讨论了过渡金属及其络合物、硒化 合物在烯丙位氧化中的应用，并简述了丁基锂方法、固相催化方法、生物氧化方法 和次氯酸钠氧化方法在烯丙位氧化中的应用．
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| 关 键 词： | 氧化 过渡金属络合物 硒化合物 次氯酸钠 应用 |
| 修稿时间： | 2002年6月21日 |
Methods of Allylic Oxidation |
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| LI,Chun SI,Yi-Kang.Methods of Allylic Oxidation[J].Chinese Journal of Organic Chemistry,2003,23(6):518-525. |
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| Authors: | LI Chun SI Yi-Kang |
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| Institution: | Institute of Materia edica,Chinese Academy of Medical Sciences & Peking Union Medical College |
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| Abstract: | Recent advances in the field of allylic oxidation are reviewed. The oxidation with transition metal, as well as selenium compounds, is the main method used in laboratory, and has been the hot point of study since 60th. In the last decade, some complexes of copper with the chiral reagents were used in the oxidation of allylic derivatives and ee% were improved obviously. The works by Muzart and Feringa using copper and chromium as the oxidants were discussed in detail. Some other methods such as using butyllithium, solid catalysis, biooxidation and sodium hypochlorite as the oxidant were also presented. |
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| Keywords: | allylic oxidation transition metal selenium |
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