Rare-earth metal alkyl and hydride complexes stabilized by a cyclen-derived [NNNN] macrocyclic ancillary ligand |
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Authors: | Ohashi Masato Konkol Marcin Del Rosal Iker Poteau Romuald Maron Laurent Okuda Jun |
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Affiliation: | Institute of Inorganic Chemistry, RWTH Aachen University, Landoltweg 1, D-52056 Aachen, Germany. |
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Abstract: | A trinuclear rare-earth metal hydride complex was synthesized from the dialkyl complex supported by a monoanionic [NNNN] macrocycle and shown to catalyze the hydrosilylation of olefins efficiently. |
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