Ion association in solutions of dimethylthallium(III) hydroxide |
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| Authors: | J. K. Lawrence J. E. Prue |
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| Affiliation: | (1) The Royal Grammar School, NE2 4DX Newcastle upon Tyne, England;(2) Department of Chemistry, University of Reading, Berkshire, England |
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| Abstract: | From studies of the specific hydroxide ion catalyzed decomposition of diacetone alcohol by dimethylthallium(III) hydroxide at 25°C, it is concluded that both ion pairs (dissociation constantK=0.090 mole-dm–3) and dimers (dimerization constantKd=1.5 dm3-mole–1) exist in aqueous solution.Request for reprints should be addressed to: Dr. A. D. Pethybridge, Department of Chemistry, The University, Whiteknights Park, Reading, Berkshire, England.Deceased October 16, 1972. |
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| Keywords: | Diacetone alcohol dimerization dimethylthallium(III) hydroxide hydroxide specific catalysis ion pairs |
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