Synthesis and luminescence properties of lanthanide complexes incorporating a hydralazine-derived chromophore |
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Authors: | Burton-Pye Benjamin P Heath Sarah L Faulkner Stephen |
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Institution: | School of Chemistry, University of Manchester, Oxford Road, Manchester, UK M13 9PL. |
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Abstract: | Reaction of 1-hydrazinophthalazine with chloroacetyl chloride yields 3-chloromethyl-1,2,4-triazolo-phthalazine. Reaction of this product with the tris tert-butyl ester of DO3A yields a triazolophthalazine appended macrocycle. Hydrolysis and complexation with lanthanide ions gives access to a series of lanthanide complexes (Ln = Nd, Eu, Yb, Er); these are all luminescent and exhibit sensitisation of the lanthanide centre by the chromophore. |
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