Nanoscale aryleneethynylene molecular wires with reversible fluorenone electrochemistry for self-assembly onto metal surfaces |
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Authors: | Wang Changsheng Batsanov Andrei S Bryce Martin R Sage Ian |
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Institution: | Department of Chemistry, University of Durham, Durham DH1 3LE, United Kingdom. |
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Abstract: | structure: see text] Two rigid-rod conjugated molecules (11 and 12) of ca. 4 and 7 nm length, respectively, bearing protected terminal thiol groups have been synthesized via multistep Sonogashira coupling reactions and shown to possess reversible cathodic solution electrochemistry arising from reduction of the fluorenone units. |
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