Chemihiminescence by the interaction of XeO3 and the products of photolysis of uranyl solutions in sulfuric acid |
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| Authors: | L. A. Khamidullina S. V. Lotnik V. P. Kazakov |
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| Affiliation: | (1) Institute of Organic Chemistry, Ufa Research Center of the Russian Academy of Sciences, 71 prosp. Oktyabrya, 450054 Ufa, Russian Federation |
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| Abstract: | Using the chemiluminescence oxidation of U(IV) and H2O2 with xenon trioxide as a model, it has been found that during the photolysis of solutions of UO2SO4 in sulfuric acid in the absence of any organic compounds, the accumulation of U(SO4)2 and H2O2 takes place as a result of the reaction of the primary products of the photoreduction of uranyl ion,i.e., UO2+ and the OH radical.Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 4, pp. 751–754, April, 1994.The work was financially supported by the Russian Foundation for Basic Research, Project 93-03-12291. |
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| Keywords: | uranyl xenon trioxide hydrogen peroxide photolysis chemiluminescence |
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