Instability of potassium permanganate solubilized in organic solvents |
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| Authors: | V Holba and J Muchová |
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| Institution: | (1) Department of Physical Chemistry, Faculty of Science, Comenius University, 842 15 Bratislava, Czechoslovakia |
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| Abstract: | The instability of the solutions of potassium permanganate solubilized in benzene, toluene and chloroform by the action of 15-crown-5, 18-crown-6, dibenzo-18-crown-6, tetra-butylammonium bromide and trilaurylmethyl ammonium bromide as phase-transfer catalysts, is reported. The kinetic parameters depend markedly on the catalyst used, the solvation of reactants is also important.
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