Solvent effect on the reactivity of arylsulfanyl radicals |
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| Authors: | G. G. Midyana R. G. Makitra E. Ya. Pal’chikova |
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| Affiliation: | 1. Physical Chemistry of Fossil Fuels Department, Litvinenko Institute of Physical Organic and Coal Chemistry, National Academy of Sciences of Ukraine, ul. Nauchnaya 3a, Lviv, 79060, Ukraine
2. Institute of Geology and Geochemistry of Fossil Fuels, National Academy of Sciences of Ukraine, Lviv, Ukraine
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| Abstract: | The rate of reaction of p-aminophenylsulfanyl radicals with styrenes decreases as a result of solvation of the initial reactants. The determining factor in the reaction with styrene is specific solvation, and in the reaction with α-methylstyrene, nonspecific solvation. |
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