Syntheses and oxidative transformations of 6-(1-methylethylidene)-3,3a,6,6a-tetrahydro-2H-cyclopenta[b]furan-2-one and its precursors |
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| Authors: | Z. R. Valiullina N. P. Akhmetdinova N. A. Ivanova O. V. Shitikova M. S. Miftakhov |
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| Affiliation: | 1. Institute of Organic Chemistry, Ufa Scientific Center, Russian Academy of Sciences, Ufa, 450054, Russia
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| Abstract: | Proceeding from the [2+2]-adduct of dichloroketene and dimethylfulvene a synthesis was developed of 6-(1-methylethylidene)-3,3a,6,6a-tetrahydro-2H-cyclopenta[b]furan-2-one, and further transformations of the latter were carried out aiming at the oxidative cleavage of the isopropylidene double bond and preparation of the corresponding cyclopentenone blocks. |
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