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Magnetic and electrical properties of intercalated phases in the (Cr, Cu)-HfSe2 system
Authors:V G Pleshchev  N V Baranov  D A Shishkin  A V Korolev  A D Gorlov
Institution:1. Gorky Ural State University, ul. Lenina 51, Yekaterinburg, 620083, Russia
2. Institute of Metal Physics, Ural Branch of the Russian Academy of Sciences, ul. S. Kovalevskoi 18, Yekaterinburg, 620990, Russia
Abstract:It has been shown that intercalation of the HfSe2 compound with chromium atoms results in an increase in the magnetic susceptibility and a decrease in the resistivity while retaining the semiconductor conductivity type. The Cr x HfSe2 compounds exhibit a paramagnetic behavior at temperatures above 2 K in the entire concentration range 0 ≤ x ≤ 0.25. It has been revealed that an increase in the electron density due to additional introduction of copper can cause the appearance of a cluster-spin-glass-type state in Cr x Cu y HfSe2 compounds. The data obtained indicate a large role of the indirect exchange interaction via conduction electrons in the formation of the magnetic state in layered intercalated compounds based on transition metal dichalcogenides.
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