Study of the addition of diazoles to vinylsilanes |
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| Authors: | V D Sheludyakov N E Kuz’mina A M Abramkin D A Cheshkov P A Storozhenko |
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| Institution: | 1. State Research Institute of Chemistry and Technology of Organoelement Compounds, sh. Entuziastov 38, Moscow, 105118, Russia
2. Research Center of Expert Assessment of Means for Medical Application, Moscow, Russia
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| Abstract: | The reaction of trimethoxy(vinyl)silane with diazoles in the presence of metal lithium was studied. The structure of the reaction products was assigned by NMR spectroscopy (1H, 13C, 29Si, COSY, NOESY, HMBC, and HSQC). An explanation for the different reactivities of reagents (aliphatic amines, diazoles, allylalkylsilanes, vinylalkylsilanes, and vinylalkoxysilanes) was provided. |
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