Hydrohalogenation of N-acetyl(aroyl)-1,4-benzoquinone monoimines |
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| Authors: | A P Avdeenko S A Konovalova O N Ludchenko O P Ledeneva A V Vakulenko |
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| Institution: | 1. Donbass State Machinebuilding Academy, Kramatorsk-13, 84313, Ukraine
2. Center of Heterocyclic Compounds, University of Florida, Gainesville, USA
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| Abstract: | New N-acetyl-1,4-benzoquinone monoimines alkyl-substituted in the quinoid ring were synthesized. The hydrohalogenation of N-acetyl(aroyl)-1,4-benzoquinone monoimines proceeds exclusively in keeping with the 1,4-addition. The hydrochlorination occurs along the ionic mechanism, in the hydrobromination grows the role of the radical mechanism. |
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