Insertion and reduction chemistry of isocyanide with a cyclometalated ditantalum hydride complex |
| |
| Authors: | Watanabe Takahito Kurogi Takashi Ishida Yutaka Kawaguchi Hiroyuki |
| |
| Affiliation: | Department of Chemistry, Tokyo Institute of Technology, Ookayama, Tokyo 152-8551, Japan. |
| |
| Abstract: | Reaction of a ditantalum hydride complex with isocyanide is reported. The hydride complex underwent single and double isocyanide insertion into Ta-H bonds, giving iminoformyl and imine-iminoacyl complexes. The transformation of the iminoformyl complex into the amido-carbyne complex was also observed. |
| |
| Keywords: | |
| 本文献已被 PubMed 等数据库收录！ |
|
