Sol鈥揼el (combustion) synthesis and characterization of different alkaline earth metal (Ca, Sr, Ba) stannates

In this study, monophasic strontium and barium stannate (SrSnO₃, Sr₂SnO₄, BaSnO₃, Ba₂SnO₄) powders were synthesized by means of environmentally friendly aqueous sol–gel technique under neutral conditions. However, it was established that the successful sol–gel synthesis of appropriate calcium stannates (CaSnO₃ and Ca₂SnO₄) can be performed only at acidic sol–gel processing conditions. Moreover, the influence of nature of alkaline earth metal source on the phase purity of different metal stannates was evaluated. The thermal behaviour of Ca–Sn–O, Sr–Sn–O and Ba–Sn–O precursor gels was investigated by TG-DSC measurements. The phase purity, crystallization peculiarities and microstructural evolution of the sol–gel derived alkaline earth metal stannate powders were studied by XRD and SEM measurements.