Synthesis of substituted dibenz[b,f]oxepines from 2,4,6-trinitrotoluene |
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| Authors: | A. V. Samet V. N. Marshalkin K. A. Lyssenko V. V. Semenov |
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| Affiliation: | 1.N. D. Zelinsky Institute of Organic Chemistry,Russian Academy of Sciences,Moscow,Russian Federation;2.A. N. Nesmeyanov Institute of Organoelement Compounds,Russian Academy of Sciences,Moscow,Russian Federation |
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| Abstract: | 1,3-Dinitro[b,f]dibenzoxepine undergoes nucleophilic substitution with O-and S-nucleophiles, the nitro group at position 1 (peri-nitro group) being selectively replaced. The factors responsible for the selectivity of the reaction are discussed. |
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