| Synthesis and Crystal Structure of Novel Fe_3 Cluster Compound |
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| 引用本文： | 陆庆玮,孙杰,等. Synthesis and Crystal Structure of Novel Fe_3 Cluster Compound[J]. 结构化学, 1996, 15(1): 31-34 |
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| 作者姓名： | 陆庆玮 孙杰 等 |
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| 作者单位： | Lu Qing-Wei; Wang Yi-Bing; Wu Bao-Shan; Suo Quan-Ling; Liu Shu-Tang; Hu Xiang; (Department of Chemical Engineering Inner Mongolia Polytechnic University，Hohhot，010062 |
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| 摘 要： | ＳｙｎｔｈｅｓｉｓａｎｄＣｒｙｓｔａｌＳｔｒｕｃｔｕｒｅｏｆＮｏｖｅｌＦｅ_３ＣｌｕｓｔｅｒＣｏｍｐｏｕｎｄ￥ＬｕＱｉｎｇ－Ｗｅｉ；ＷａｎｇＹｉ－Ｂｉｎｇ；ＷｕＢａｏ－Ｓｈａｎ；ＳｕｏＱｕａｎ－Ｌｉｎｇ；ＬｉｕＳｈｕ－Ｔａｎｇ；ＨｕＸｉａｎｇ；（Ｄｅ?..
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| 关 键 词： | 合成 晶体结构 铁配合物 三铁簇形化合物 氰基配位体 |
Synthesis and Crystal Structure of Novel Fe3 Cluster Compound |
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| Lu Qing-Wei, Wang Yi-Bing, Wu Bao-Shan, Suo Quan-Ling, Liu Shu-Tang, Hu Xiang,. Synthesis and Crystal Structure of Novel Fe3 Cluster Compound[J]. Chinese Journal of Structural Chemistry, 1996, 15(1): 31-34 |
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| Authors: | Lu Qing-Wei Wang Yi-Bing Wu Bao-Shan Suo Quan-Ling Liu Shu-Tang Hu Xiang |
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| Affiliation: | [1]DepartmentofChemicalEngineeringInnerMongoliaPolyte [2]DepartmentofChemicalEngineeri |
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| Abstract: | The title compound Fe_3 (CO)_8(CN)S_2 was synthesized by the reaction of C_6H_5NCS cleaving fragments with Fe_3 (CO)_(12) at room temperature. Crystal data: C_9Fe_3NO_8S_2, Mr=481. 76, triclinic , space group P1,a= 9. 436 (3), b=10. 210(2), c=9. 14l(3) A, a =90. 63(2), β=117. 55(3), γ=96. 66(2)°, V=773. 5(4) A￣3 , Z=2, D_c= 2. 068 g/cm￣3, μ(MoKa)=30. 78 cm￣(-1), F(000)=470 .T= 293K , final R=0. 030 and R_w=0. 041 for 2314 observed reflections with I>3. 00 σ(I).The monosubstituted ligand(CN)in Fe_3 (CO)_8 (CN)S_2 is linked to basal Fe (3) atom of the distorted tetragonal pyramid Fe_3S_2 framework. |
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| Keywords: | synthesis crystal structure iron cluster cyano ligand |
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