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1.
Yalda Liaghati Mobarhan Ronald Soong Daniel Lane Andre J. Simpson 《Magnetic resonance in chemistry : MRC》2020,58(5):427-444
Traditionally, due to different hardware requirements, nuclear magnetic resonance (NMR) has developed as two separate fields: one dealing with solids, and one with solutions. Comprehensive multiphase (CMP) NMR combines all electronics and hardware (magic angle spinning [MAS], gradients, high power Radio Frequency (RF) handling, lock, susceptibility matching) into a universal probe that permits a comprehensive study of all phases (i.e., liquid, gel-like, semisolid, and solid), in intact samples. When applied in vivo, it provides unique insight into the wide array of bonds in a living system from the most mobile liquids (blood, fluids) through gels (muscle, tissues) to the most rigid (exoskeleton, shell). In this tutorial, the practical aspects of in vivo CMP NMR are discussed including: handling the organisms, rotor preparation, sample spinning, water suppression, editing experiments, and finishes with a brief look at the potential of other heteronuclei (2H, 15N, 19F, 31P) for in vivo research. The tutorial is aimed as a general resource for researchers interested in developing and applying MAS-based approaches to living organisms. Although the focus here is CMP NMR, many of the approaches can be adapted (or directly applied) using conventional high-resolution magic angle spinning, and in some cases, even standard solid-state NMR probes. 相似文献
2.
Xiao‐Dong Pan 《Journal of Polymer Science.Polymer Physics》2004,42(13):2467-2478
For properly chosen elastomer compounds, thermorheological characterization is combined with an examination of the variation of the wet sliding friction with temperature. A conceptual argument leads to the assumption that the wet sliding friction should maximize at the energy dissipation peak associated with the dynamic softening transition at a characteristic frequency determined by the sliding speed and the effective smallest surface asperity scale. The dynamic softening transition is characterized with the peak in tan δ/G′n, where tan δ is the loss tangent, G′ is the elastic modulus, and n is a constant between 0 and 1. The William–Landel–Ferry transform is uncritically applied for extrapolating the position of the peak in tan δ/G′n at high frequencies. Even based on the criterion of tan δ, the results obtained on a concrete surface indicate that the effective smallest asperity scale is of order of 100 μm. © 2004 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 42: 2467–2478, 2004 相似文献
3.
魏幼平 《东华大学学报(英文版)》1993,(4)
The technique of sirospun process is applied on a modified semi-worsted balloonless spinningframe to investigate the effect of spindle-speed,yarn-twist and strand-spacing on yarn properties.Yarn breaking strength,breaking extension,evenness and imperfection are examined on the basisof CCD experimental design.Yarn hairiness is particularly concerned,being found that all spinningparameters tested have significant effects on hairiness and that the minimum number of hairs oc-curs at the strand-spacing of 14.4 mm.Compared to conventional single spun yarn,experimentshave revealed the greatest advantage of using sirospun process is that all sirospun yarns have muchless hairiness.A new sirospun yarn fault,so called“loop”,has also been examined.The most likely cause forthis yarn fault is the strand-tension unbalance between the two strands when low tension spinningis applied.Further analysis and some initial tests have been carried out in the hope of overcomingthis loop fault which is an important obstacle to the application of balloonless spinning. 相似文献
4.
何瑶 《武汉科技学院学报》2002,15(5):7-10
采用蒸发和吸湿法测量多种织物的透湿速率,并且仔细研究用蒸发法时,织物润湿程度在透湿过程中的变化,发现织物在透湿过程中的润湿和放湿,以及织物的表面性状是影响其放湿速率的非常重要的因素。 相似文献
5.
This paper develops a mathematical model of the ring-spinning process that takes into account its non-stationary nature. A complex system of differential equations is obtained, which from a mathematical point of view constitutes a ‘free-boundary’ problem. Its solution involves definition of suitable boundary conditions related to the mechanical characteristics of the process and of the spinning machine itself. The boundary conditions which determine the solution are pointed out. A numerical solution of the system of differential equations can be obtained by the Finite-Segments method, as shown in an example. 相似文献
6.
The effect of colorant additive on the rheology of PP polymer melt and the influence of spinning conditions on the crystalline and orientation structure of mass-dyed as-spun PP filament are reported. The △E~~~ value for all colored chips is higher than that of blank chip to a varying degree. The crystallinity and orientation degree of dyed PP as-spun filament decrease with increasing melt temperature, decreasing spinning speed and increasing denier per filament (dpf), while the crystallinity of dyed as-spun filament increases with the content of colorant additive as a nucleation agent. 相似文献
7.
本文研究了在管道纺纱机上不添加构件而进行包芯纱的纺制。分析了其包芯纱的成纱机理。观察了实际成纱的横截面,证实了棉纤维能够均匀地、完全地包覆在芯丝的周围。也对不同性质的芯丝所纺包芯纱的结构作了观察,并对不同成纱的性质随速度增加而变化的规律作了研究。 相似文献
8.
研究了金属间化合物快速凝固薄带的成型过程和影响薄带质量的工艺参数。提出了熔体在喷嘴处进行层流流动的经验关系式,给出了金属间化合物快速凝固薄带制备的最佳工艺参数。 相似文献
9.
刘国涛 《南通大学学报(自然科学版)》2002,1(2):20-25
二十一世纪,一些相关高新技术的发展和应用,将对传统工程产生巨大的影响和推动。文章在此基础上,对新世纪前半叶纺纱技术、纺纱设备以及纺纱工厂自动化的发展进行了展望。 相似文献
10.