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任世斌 《山西师范大学学报:自然科学版》2006,20(1):73-75
以蓖麻油为原料,以酯交换反应来合成壬二酸单乙酯,利用IR和^1HNMR对化合物结构进行了表征,讨论反应时间和反应温度对酯交换反应的影响. 相似文献
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The miscibility has been investigated for binary blends of a polyarylate (PAr) with a liquid crystalline copolyester of p-hydroxybenzoate and ethylene terephthalate units in a 6/4 molar ratio (PET/PHB). The binary blends were prepared by solution precipitation. The transitions of the PET/PHB have been measured with a rheometrics dynamic spectrometer. The phases in blends have been studied with a differential scanning calorimeter, by ther-mogravimetry and with a polarizing optical microscope. The blends exhibit two glass transitions (Tgs) over the composition range 10–90 wt %. The amorphous PET phase from the PET-PHB is found to be partially miscible with PAr, which leads to a decrease of the PAr Tg. The amount of this partially miscible portion of PET has been estimated by the Couch-man equation. On heat treatment of the blends at 250 to 300°C, transesterficiation takes place, as judged by the shift of the higher of the two Tgs. © 1993 John Wiley & Sons, Inc. 相似文献
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