全文获取类型
收费全文 | 1895篇 |
免费 | 243篇 |
国内免费 | 402篇 |
专业分类
化学 | 1431篇 |
晶体学 | 29篇 |
力学 | 23篇 |
综合类 | 10篇 |
数学 | 76篇 |
物理学 | 194篇 |
综合类 | 777篇 |
出版年
2024年 | 3篇 |
2023年 | 13篇 |
2022年 | 23篇 |
2021年 | 49篇 |
2020年 | 53篇 |
2019年 | 45篇 |
2018年 | 57篇 |
2017年 | 63篇 |
2016年 | 68篇 |
2015年 | 102篇 |
2014年 | 104篇 |
2013年 | 118篇 |
2012年 | 140篇 |
2011年 | 158篇 |
2010年 | 132篇 |
2009年 | 145篇 |
2008年 | 176篇 |
2007年 | 174篇 |
2006年 | 187篇 |
2005年 | 160篇 |
2004年 | 165篇 |
2003年 | 100篇 |
2002年 | 58篇 |
2001年 | 56篇 |
2000年 | 45篇 |
1999年 | 21篇 |
1998年 | 28篇 |
1997年 | 24篇 |
1996年 | 12篇 |
1995年 | 12篇 |
1994年 | 12篇 |
1993年 | 7篇 |
1992年 | 7篇 |
1991年 | 7篇 |
1990年 | 3篇 |
1989年 | 5篇 |
1987年 | 2篇 |
1986年 | 1篇 |
1985年 | 1篇 |
1984年 | 1篇 |
1983年 | 1篇 |
1979年 | 2篇 |
排序方式: 共有2540条查询结果,搜索用时 718 毫秒
1.
针对“剥岩高峰”对矿山生产带来的不利影响,研究了设备配置更新策略与露天开采外委剥离的优化问题.基于铲运设备的运营成本与生产能力随设备役龄变化的关系,建立了决策单台设备退役时间的动态经济寿命计算模型,并根据此模型给出了具体的设备配置算法步骤.设置一系列不同的矿山自剥离量与外委剥离量的分界水平,计算各分界水平条件下的外委单价可行区间,然后在区间内确定外委商谈价格并分析得出与之对应的总成本净现值最低的外委方案.实例计算证明,采用该方法减少设备投资的成本要高于外委岩石剥离成本. 相似文献
2.
3.
A stochastic approximation algorithm for estimating multichannel coefficients is proposed, and the estimate is proved to converge to the true parameters a.s. up-to a constant scaling factor. The estimate is updated after receiving each new observation, so the output data need not be collected in advance. The input signal is allowed to be dependent and the observation is allowed to be corrupted by noise, but no noise statistics are used in the estimation algorithm. 相似文献
4.
C. A. Beattie M. B. Boisen Jr. L. W. Johnson 《Journal of Optimization Theory and Applications》1991,68(1):203-203
Corrections to the last two equations of Ref. 1 are given. 相似文献
5.
孙鸿烈 《辽宁大学学报(自然科学版)》1992,19(4):17-23
本文利用解非线性方程组的列修正拟Newton法给出了常微分方程数值解法中的Adams内插公式的并行计算方法,并证明了该方法的收敛性 相似文献
6.
基于软件内建自测试的模板和基准程序设计 总被引:7,自引:0,他引:7
论述了软件内建自测试项目中“模板”模块的设计方法,利用硬件测试中所使用的基准电路的思想,研究并开发了一种基准程序,使用这种基准程序,可以较为方便地对所生成的测试用例进行测试,最后给出了一个基准程序实例。 相似文献
7.
Huadong Tang Maciej Radosz Youqing Shen 《Journal of polymer science. Part A, Polymer chemistry》2006,44(22):6607-6615
Uracil‐derivatized monomer 6‐undecyl‐1‐(4‐vinylbenzyl)uracil and diaminopyrimidine‐derivatized monomer 2,6‐dioctanoylamido‐4‐methacryloyloxypyrimidine (DMP) were synthesized and polymerized by atom transfer radical polymerization (ATRP). A well‐defined, highly soluble, uracil‐containing polymer, poly[6‐undecyl‐1‐(4‐vinylbenzyl)uracil] (PUVU), was prepared in dioxane at 90 °C with CuBr/1,1,4,7,10,10‐hexamethyltriethylenetetramine as the catalyst and methyl α‐bromophenylacetate as the initiator. PUVU was further used as a template for the ATRP of DMP. The enhanced apparent rate constant of the DMP polymerization in the presence of PUVU indicated that the ATRP of DMP occurred along the PUVU template. The template polymerization produced a stable and insoluble macromolecular complex, PUVU/poly(2,6‐dioctanoylamido‐4‐methacryloyloxypyrimidine). An X‐ray diffraction study confirmed that the complex had strandlike domains. © 2006 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44: 6607–6615, 2006 相似文献
8.
9.
甲酰胺对有序介孔二氧化硅形貌的影响 总被引:2,自引:0,他引:2
At room temperature and in acidic solution, ordered mesoporous silicas with particular morphology were synthesized using cetylpyridinium chloride as the template and formamide as the cosolvent. Scanning electron microscope (SEM), small angle X-ray diffraction (SXRD), and nitrogen adsorption techniques were used to characterize the as-synthesized and calcined samples. Results showed that the samples had hexagonal mesostructure analogous to MCM-41 and relatively narrow pore-size distributions (BJH). Besides, BET surface areas of the samples were in the range of 1 000~1 250 m2·g-1 and high total pore volumes were up to 1.367 cm3·g-1. Addition of formamide affected obviously mesostructures and the morphology of the mesoporous silica. Furthermore, with the increase of the concentration of formamide, the unit-cell constant decreased and particle shape changed from gyroids to fibers. 相似文献
10.
Substantial progress has been made recently in extending the supramolecular assembly of biomimetic structures to vesicle-based sophisticated nanocomposites and mesostructures. We report herein the successful preparation of unilamellar surfactant vesicles coated with a monolayer of ring-shaped [Mo(154)] polyoxometalate (POM) nanoclusters, (NH(4))(28)[Mo(154)(NO)(14)O(448)H(14)(H(2)O)(70)]. approximately 350 H(2)O, by coulomb attractions using preformed didodecyldimethylammonium bromide (DDAB) surfactant vesicles as templates. The resultant vesicle-templated supramolecular assemblies are robust (they do not disintegrate upon dehydration) both at room-temperature ambient and vacuum conditions, as characterized by conventional transmission electron microscopy (TEM) and atomic force microscopy (AFM). The flexibility of the complex soft assemblies was also revealed by AFM measurements. The effect of POM-vesicle coulomb attractions on the dimensions of the templating vesicles was also investigated by using dynamic light scattering (DLS). Although origins of the structure stability of the as-prepared supramolecular assemblies are not clear yet, the nanometer scale cavities and the related properties of macroions of the POM clusters may play an important role in it. 相似文献