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1.
Felix Franks 《Journal of solution chemistry》1995,24(11):1093-1097
At a recent meeting of the International Symposium on Solution Chemistry I presented a paper dealing with aqueous solutions in which water was present not in excess but as one component of a supersaturated solution with polyhydroxy compounds. In response to a request from the Editor of this Journal I have submitted this article in which I outline my general interest in the subject and its importance as a new direction for solution chemists. 相似文献
2.
描绘了胆固醇型结石形成过程中胆固醇结晶的生化图景。着重从相变动力学的角度对过饱和胆汁结晶过程进行了分析,提出了可能的结晶机制。通过简化的模型.,给出了结晶推动力,并绘制了可能的C-X图。△Gs,△Gn,△Gnuc的提出可能促进促、抗成核因子的相关研究。 相似文献
3.
《Analytical letters》2012,45(4):314-329
In the last 10 years researchers have adapted a number of instrumental techniques for studying various aspects of historical inks that have been used in historical documents. In this paper, the applications of atomic spectroscopy such as GFAAS, ICP-MS, XRF, PIXE, and XANES are described for identifying and quantifying metals that are found in historical inks. Applications of vibrational spectroscopy, primarily Raman and near/mid-IR spectroscopy, are described for detecting organic and inorganic compounds in ink and paper. 相似文献
4.
FT-Raman, FTIR, and SERS spectra of the structurally related gallnut polyphenols tannic acid, gallic acid, pyrogallol, and syringic acid are reported in this work aiming at performing a comparative assignation of the bands and finding specific marker features that can identify these compounds in complex polyphenol mixtures. Tannic and gallic acids are the principal components in oak gallnuts, and they can be found in iron gall inks. The different functional groups existing in these molecules and their spatial distribution lead to slight changes of the vibrations. The Raman spectra are dominated by bands corresponding to the ring vibrations, but the substituents in the ring strongly affect these vibrations. In contrast, the FTIR spectra of these molecules are dominated by the peripheral oxygen-containing substituents of the aromatic ring and afford complementary information. SERS spectroscopy can be used to analyze trace amounts of these compounds, but the spectra of these polyphenols show strong changes in comparison with the Raman spectra, indicating a strong interaction with the metal. The most significant modification observed in the SERS spectra of these compounds is the weakening of the benzene 8a ring vibration and the subsequent intensification of the 19a mode of the benzene ring. This mode is also more intense in the FTIR spectra, and its intensification in the SERS spectra could be related to a drastic change in the molecular polarizability associated with the interaction of the polyphenol with the metal in Ag NPs. 相似文献
5.
吴次彬 《四川大学学报(自然科学版)》1992,29(4):530-534
对在我国西南地区发展白蜡虫、紫胶虫、五倍子蚜虫及马桑蚕等林业资源昆虫的意义、培育利用概况,以及作好区划,因地制宜地加以发展等问题作了探讨. 相似文献
6.
利用化学还原法制备了含有少量硼的过饱和Fe-Cu固溶合金。fcc相的固溶度被扩展至铁含量接近80%,大大超过了用其它方法制备所能达到的固溶度,并且在退火过程中fcc结构相当稳定。fcc相的扩展以及相当高的稳定性与硼的存在有关。 相似文献
7.
8.
熊胆等几种动物胆中氨基酸的色谱—质谱分析 总被引:3,自引:0,他引:3
采用化学衍生化和GC-MS分析技术,测定了熊胆,牛胆,猪胆,羊胆中的氨基酸,经计算机检确定了14种。并通过氨基酸的标准样品进行了定量,从14种氨基的分布来看,熊胆与其他3种胆的差异较大,为我们鉴别真假提供了一个新的有参考价值的依据。 相似文献
9.
In the present work, an investigation has been conducted by electrospray ionization (ESI) experiments to characterize the structures of iron gall ink complexes in solution. Simple mono and polyphenolic acid molecules added to iron sulfate salts were chosen to model the recipes of ink composition. Theoretical calculations have been used (1) to determine the stability of the ionic complexes generated in the gas phase, (2) to explain which structures are more likely generated in the electrospray ion source, and (3) to determine which mechanisms are likely involved in their formation. Fragmentation pathways of the derived structures have also been investigated and rationalized to facilitate the interpretation of the data obtained under collisionally induced dissociation (CID) conditions.The present study confirms the assumption that ESI experiments with ions that are preformed in solution must be considered carefully. As a matter of fact, the study of ion formation mechanisms in the ion source is necessary to establish relationships between the ion structures in the condensed phase and the gas phase. 相似文献
10.
高硅铝合金粗大的初晶硅严重影响其力学性能与机械加工性能.本文利用熔融纺丝快速凝固技术、球磨与放电等离子烧结相结合的方法制备了Al75Si25合金.研究发现,放电等离子烧结Al75Si25能够遗传其快速凝固组织的特点.500 MPa,320℃烧结条件可获得密度达到98%以上的块体,其初晶硅弥散分布,组织尺寸细小,具有超细晶粒特征.此外,硅元素过饱和固溶于α(Al)基体.维氏硬度值和抗压强度分别达到298 Hv和674 MPa,具有优异的力学性能. 相似文献