Determination of sulfa antibiotic residues in river and particulate matter by field-amplified sample injection-capillary zone electrophoresis

In the present research, field-amplified sample injection–CZE (FASI–CZE) coupled with a diode array detector was established to determine trace level sulfa antibiotic. Sulfathiazole, sulfadiazine, sulfamethazine, sulfadimethoxine, sulfamethoxazole, and sulfisoxazole were selected as analytes for the experiments. The background electrolyte solution consisted of 70.0 mmol/L borax and 60.0 mmol/L boric acid (including 10% methanol, pH 9.1). The plug was 2.5 mmol/L borax, which was injected into the capillary at a pressure of 0.5 psi for 5 s. Then the sample was injected into the capillary at an injection voltage of –10 kV for 20 s. The electrophoretic separation was carried out under a voltage of +19 kV. The capillary temperature was maintained at 20˚C throughout the analysis, and six sulfonamides were completely separated within 35 min. Compared with pressure injection-CZE, the sensitivity of FASI-CZE was increased by 6.25–10.0 times, and the LODs were reduced from 0.2–0.5 to 0.02–0.05 μg/mL. The method was applied to the determination of sulfonamides in river water and particulate matter samples. The recoveries were 78.59–106.59%. The intraday and interday precisions were 2.89–7.35% and 2.77–7.09%, respectively. This provides a simpler and faster method for the analysis of sulfa antibiotic residues in environmental samples.     

基于突变级数法的福州市某区土壤重金属污染综合评价

以福州市某区土壤为研究对象,采用突变级数法对福州市某区土壤重金属污染进行评价,依据主成分分析对评价因子进行选择,整个评价指标体系避免了人为确定权重的主观性.结果表明:福州市某区土壤重金属污染目前整体呈现一个较为良好的态势,但有部分地区处于"病态"状况.距离该区中心较近的西客站、李园天桥、远洋以及于山、东街口到靠近郊区的燎原、三角埕、鼓山等地的污染的综合隶属值呈递增的趋势,表明距离城市中心越近的土壤重金属污染越为严重.     

多元有序地质数据的最优分割法在工程中的应用

采用数学地质理论中的多元有序地质数据的最优分割方法对工程场地松散岩土层亚层进行了划分。实践证明 ,在土样物理力学性能评价指标选取合理的前提下 ,该方法简单方便 ,行之有效 ,可作为一种辅助手段帮助地质人员开展对土层的详细研究     

豫西丘陵区不同氮、钾肥用量配施对豫麦47号品质和产量的影响

在该试验条件下 ,豫麦 47号的湿面筋含量平均为 2 8.3%,吸水率、面团形成时间、稳定时间分别为 6 3.2 %、3.9分钟和 4.2分钟 ,与豫麦 47号适生区栽培条件下均有较大差异。氮肥可有效提高豫麦 47号的冬前分蘖、亩有效穗数和湿面筋含量 ,钾肥可提高亩穗数和千粒重。     

稻砂土吸附铜镍铅砷能力的比较

通过对砂壤水稻土中Cu,Ni,Pb,As4种元素的单元及复合吸附试验,表明其吸附热力学符合Freundlich方程,吸附能力为Pb Cu>As>Ni.共存元素对土壤吸附某一元素的能力影响不大;用Langmuir方程粗略地估算出这4种元素在土壤中的化学容量.     

Resistivity－temperature characteristics of sol gel YBa2Cu3Oy samples synthesized in flowing oxygen atmosphere

The relationship of resistivity versus synthesizing temperature of sol gel YBa_2Cu_3O_y samples was studied when prepared under flowing oxygen conditions. A set of high-temperature ρ－T curves was obtained for the whole process. After the sample finished the test measuring, its resistivity was ρ_{300}=9.83×10^{-3 }Ω·cm at room temperature. The ρ－T curve also showed that the orthorhombic－tetragonal phase transformation of sol-gel YBa_2Cu_3O_y sample occurred at 581℃ for the sample in the rising temperature process, but at 613℃ in the cooling process, lower than that of the samples made by using the conventional powder metallurgy methods.     

污泥营养土对菊花营养生长和开花的效应

采用三种菊花的盆栽试验，探讨不同配比的污泥营养土对三种菊花冠径、地径和生物量、叶绿素含量、花期、开花量等的影响，结果表明：2份污泥＋14份塘土＋3份炉渣＋3份谷壳灰和3份污泥＋3份炉渣＋3份谷壳灰的污泥营养土配方，能显著促进菊花的营养生长，延长花期，增加花量，施用效果最好。     

长白山土壤腹足类物种多样性初步研究

自1993年5月至10月对吉林长白山森林生态系统定位站的土壤腹足类进行了多样性调查，据初步调查的结果显示，长白山地区土壤腹足类种类少而单调，采样区仅发现15种，隶属于腹足纲9科13属，采样区土壤腹足类物种多样性指数和丰富度指数都是5月份最低，8月份达最大值，之后逐渐减小；均匀度指数5月份最高，7月份最低；单纯度指数也是5月份最高，最低值出现在10月份，土壤表层的陆生贝类物种多样性指数高于上层。     

大同盆地盐碱土综合治理效果及治理经验

介绍了大同盆地的盐碱类型及分布特点,分析了大同盆地盐碱土综合治理效果,阐述了大同盆地盐碱土综合治理的经验。