癸二酸聚氧乙烯十二醇酯的合成及应用

本文介绍了将癸二酸先与单分子的十二醇进行酯化反应,所得产物再与不同摩尔比的环氧乙烷进行缩合,最终得到的非离子型表面活性剂可应用于涤棉织物的柔软整理。     

In-time motion adjustment in laser cladding manufacturing process for improving dimensional accuracy and surface finish of the formed part

This paper presents in-time motion adjustment in laser cladding manufacturing process as a means to improve dimensional accuracy and surface finish of the built part. Defects occurring during laser cladding degrade the part quality such as dimensional accuracy and surface finish. In this paper, in-time motion adjustment strategy was presented to remedy and eliminate defects occurring during laser cladding to improve the dimensional accuracy and surface finish. Based on the relationship between the motion of laser head relative to the growing part and other parameters in effects on clad profile, the laser traverse speed, stand-off distance and laser approach orientation to the existing clad layer were adjusted by instructions from a close-loop control system in real time to remedy and eliminate defects. The results of the experiments verified the effects of in-time motion adjustment on dimensional accuracy and surface finish.     

低场脉冲核磁共振测定二醋酸纤维素丝束中油剂

研究了采用低场脉冲核磁共振(NMR)测定二醋酸纤维素丝束油剂的新方法，给出NMR法测定二醋酸纤维素丝束油荆含量的标准曲线。同时对NMR法测量二醋酸纤维素丝束油荆不确定度进行了评估。结果表明，NMR法具有分析速度快、无污染、无损伤和准确度高的优点，适合于二醋酸纤维素丝束油荆的分析。     

清水混凝土施工工艺在市政桥梁工程中的应用

城市桥梁外观质量在城市美化建设中越来越重要。以太原市柴村大桥为例,详细介绍了清水混凝土的施工工艺及应用,以期对今后同类型施工有一些借鉴作用。     

天然彩棉织物的无甲醛抗皱整理

采用柠檬酸为交联剂,对天然彩棉织物进行无甲醛抗皱整理.经正交实验,优选出了交联剂、催化剂、添加剂用量以及最佳工艺条件.最佳工艺条件为:柠檬酸8%,催化剂(柠檬酸钠和酒石酸钠)12%,三乙醇胺4%,JFC 2 g/L,温度170℃,时间90 s,浴比1∶20.实验表明,经柠檬酸整理后天然彩棉针织物的抗皱性能得到了明显的改善。     

强激光冲击锻铝薄板的实验

进行了锻铝合金(LD31)薄板试样在短脉冲强激光冲击下的实验研究.结果表明:在强激光冲击下,试样发生显著的塑性变形,变形后轴截面形状为类圆锥形;试样塑性变形量随激光能量的增加而增加,随着试样的厚度增加而减小;在其他工艺参数相同的情况下,圆形试样比正方形试样更容易发生塑性变形;试样冲击变形区正反二面表面粗糙度值下降,表面光洁度得到明显提高;试样冲击区的硬度没有得到显著提高,这和冲击强化有着很大不同;当激光能量的增加或者试样厚度减薄到一定程度时,试样将发生层裂,从其断口的形貌来看,其断裂方式属于韧性断裂.     

旧水泥混凝土路面沥青罩面层反射裂缝的防治

从旧水泥混凝土路面沥青罩面层反射裂缝的形成机理、防治措施入手,阐述了在施工时设置应力吸收层的必要性,并重点论述了玻纤格栅应力吸收层的特点及其在施工中的应用。     

等离子体对壳聚糖整理棉织物效果的影响

研究等离子体预处理技术对棉织物壳聚糖功能整理效果的影响.比较3种不同的整理方法.第1种是用柠檬酸及壳聚糖的混合溶液进行一浴整理;第2种是先用柠檬酸溶液再用壳聚糖溶液进行两浴处理;第3种是使用等离子体预处理织物后再经两浴法整理.使用酸性橙Ⅱ对整理后织物染色并测试K/S值.通过测试织物大肠杆菌和金黄色葡萄球菌的抗菌率考察其抗菌性.结果表明,经等离子体预处理后再经两浴法整理的织物的K/S值以及抗菌率较一浴法或两浴法都有所提高,对大肠杆菌和金黄色葡萄球菌的抗菌率高达100%.     

Oxidation kinetics of thin copper films and wetting behaviour of copper and Organic Solderability Preservatives (OSP) with lead-free solder

The oxide formation on thin copper films deposited on Si wafer was studied by XPS, SEM and Sequential Electrochemical Reduction Analysis SERA. The surfaces were oxidized in air with a reflow oven as used in electronic assembly at temperatures of 100 °C, 155 °C, 200 °C, 230 °C and 260 °C. The SERA analyses detected only the formation of Cu₂O but the XPS analysis done for the calibration of the SERA equipment proved also the presence of a CuO layer smaller than 2 nm above the Cu₂O oxide. The oxide growth follows a power-law dependence on time within this temperature range and an activation energy of 33.1 kJ/mol was obtained. The wettability of these surfaces was also determined by measuring the contact angle between solder and copper substrate after the soldering process. A correlation between oxide thickness and wetting angle was established. It was found that the wetting is acceptable only when the oxide thickness is smaller than 16 nm. An activation energy of 27 kJ/mol was acquired for the spreading of lead free solder on oxidized copper surfaces.From wetting tests on copper surfaces protected by Organic Solderability Preservatives (OSP), it was possible to calculate the activation energy for the thermal decomposition of these protective layers.     

拒油防污防缩整理工艺研究

用中心旋转法设计了防皱整理剂RESIN BRT、拒油防污剂PM-492和氯化镁3个变量、5个水平的20个试验.通过分析试样的折皱回复角、释放甲醛量、撕破强力保留率的等值图,确定了较佳的拒油防污防缩整理工艺：防皱整理剂RESIN BRT 80～85 g/L,拒油防污剂PM-492 40 g/L,MgCl2.6H2O 12～13 g/L,整理液pH值4.2,二浸二轧,105～110℃下预烘3 min,165～170℃下焙烘2 min.整理后衬布的拒水拒油性能达到120分,水洗尺寸变化率为-0.7%,热熔衬布释放甲醛量小于40 mg/kg,折皱回复角大于270°,衬布的质量符合优等品的要求.