Qualitative interpretation of physico-chemical and isotopic parameters in the Krka River (Croatia) assessed by multivariate statistical analysis

Multivariate statistical analyses were applied on the measured physico-chemical (Cd, Pb, Cu, Zn, Mg, Ca, O₂, alkalinity, temperature, pH, SAS, DOC and DIC) and isotopic parameters (δ¹³C and δ¹⁸O) to estimate and distinguish anthropogenic from natural influences to the water system of the Krka River. Analyses were conducted on the data collected during six years from twelve sampling sites. On the basis of orientation, positioning and grouping of parameters arranged by biplots, four main hypotheses were defined and finally statistically confirmed. Thereof, two main and distinct processes occurring in the Krka River could be highlighted: (i) upstream pollution, caused by the inflow of untreated waste-waters of city of Knin and (ii) downstream self-purification, caused by the sedimentation and/or co-precipitation of pollutants coupled by the inflow of clean subterranean water (groundwater recharge). Grouping of (i) hydrological and carbon cycle connected parameters, and (ii) anthropogenically influenced correlated parameters were proposed as a result of statistical analysis. Regarding the pH, it is shown that a stream section influenced by the subterranean inflow of Zrmanja River is statistically significantly different for all sampling campaigns during six years, being lower for about 0.5 pH unit.     

广西里湖地下河水化学特征及其影响因素

【目的】岩溶地下水由于储量相对丰富,水质优良,是良好的供水水源。因此,揭示岩溶地下水水化学特征及其影响因素,能够为保护和利用岩溶地下水提供科学依据。【方法】以广西里湖地下河为研究对象,于不同季节对里湖地下河上游到下游的河水进行水化学分析。【结果】里湖地下河水主要阴离子为HCO-3,主要阳离子为Ca2+,水化学类型为HCO3-Ca型,影响水质变化的主要离子为Cl-,NO-3,SO2-4;各离子浓度从上游到下游变化不一致,总体呈现先升高再降低的趋势,季节变化体现在雨季离子浓度偏低,旱季偏高。【结论】地下水地球化学组成受控于碳酸盐岩的自然风化溶解;污染物质主要来源于人类活动的输入,降雨的稀释作用是影响水质季节性变化的主要原因,地下河自身存在的自净能力使得污染物浓度降低,尤其是甘田坝到小龙洞洞穴伏流段水体中部分污染物的浓度显著降低。     

几种矿物相在重金属类污染物自净化体系中的应用

自然界中的许多矿物自身赋有容纳和稳定有害物质的自净化能力,可用于重金属类污染物的治理。水滑石类层状双氢氧化物LDH体系(layer double hydroxide)、托勃莫来石类水化硅酸钙(calcium silicate hydrate)和磷灰石(apatite)是自然界中普遍存在的3种矿物相,具有较高的地球化学稳定性和潜在的重金属自束缚稳定能力。在阐述3种矿物相晶体结构特点和自净化原理的基础上,对它们在危险废物污染物自净化体系中所起的作用进行了讨论。     

苏州河道水污染原因及其防治对策分析

当前苏州河道水环境污染问题突出，严重危及城市形象。本文认为污染物的大量排放和河道自净能力的降低是造成苏州古城区河道水污染的主要原因，并针对此提出加强工程与非工程建设相结合的综合防治对策。     

黄河环境流研究

河流的环境流是指在维持河流自然功能和社会功能均衡发挥的前提下,能够将河流的河床、水质和生态维持在良好状态所需要的河川径流条件.结合黄河特点,分别分析了维持下游和宁蒙河段良好主槽、兰州以下河段全面实现Ⅲ类水、重要保护鸟类或鱼类的种类或数量恢复到20世纪90年代初期水平3方面所需要的径流条件.并充分考虑黄河应承担的社会功能,给出了现阶段可基本实现黄河自然功能和社会功能均衡发挥的各河段环境流建议.     

宫崎骏动漫作品审美探析

宫崎骏创作审美意识中较多地表现了其自身的审美价值取向，在作品中蕴含了现代意义上“善与恶”对立的思考。文章主要对宫崎骏动漫作品中所传达的审美观及审美主题进行探讨，试图揭示“善与恶”在宫氏动漫作品中的审美内涵，以期对审美现代性及艺术美学探索有所启示。     

A Novel in Situ Oxidization-Sulfidation Growth Route via self-Purification Process to β-In2S3 Dendrites

A novel in situ oxidization-sulfidation growth route via a self-purification process has been developed to synthesize β-In₂S₃ dendrites. To our best knowledge, this is the first example to prepare dendrites of III-VI compounds, which are expected to show particular physical properties. The X-ray analysis (EDXA), X-ray photoelectron spectra (XPS), Raman spectrum and optical properties of β-In₂S₃ dendrites have also been investigated. It is found that the product is pure In₂S₃ and shows the strong quantum confinement of the excitonic transition expected for the In₂S₃ dendrites.     

Practice and design of the self-purification system for heavy metals-bearing contaminants

Many minerals in nature have self-purification capacity to hold and stabilize deleterious contaminants into their lattice structures, which can be used for treatment of heavy metals-bearing contaminants. Hydrotalcite Layer Double Hydroxide （LDH）, tobermorite Calcium Silicate Hydrate （CSH） and apatite are ubiquitous minerals in nature, having higher geochemical stability and potential for binding and stabilizing heavy metals. Based on the elucidation of crystal structure property and self-purification principles of the three minerals above, this article discussed how to design the self-purification system of heavy metal-bearing contaminants.