Mono-dispersed cross-linked polystyrene micro-spheres prepared by seed swelling polymerization method

A two-step swelling procedure was adopted to synthesize mono-dispersed and highly cross-linked poly (St-divinylbenzene) particles with PSt micro-spheres (1.80 μm in diameter). The PSt micro-spheres were prepared by a dispersion polymerization method and used as seeds. The effects of monomer concentration, ratio of ethanol to water, swelling reagents, crosslinking reagents, swelling temperature and agitation speed on particle size were investigated in detail. The morphologies and size distributions of these micro-spheres were examined by SEM and particle size analysis (PSA). The T _g of the micro-spheres was measured by DSC. The results indicate that the particles (6.20 μm in diameter) exhibit excellent mono dispersed property and high crosslinking degree when the concentration of the swelling reagent was 25%, the concentration of the crosslinking reagents was 23%, the swelling temperature was 30°C and the stirring speed was 150 r/min. __________ Translated from Chinese Journal of Applied Chemistry, 2007, 24(11): 1289–1294     

新疆野生黑加仑与马林果实的营养成分分析

通过对新疆野生黑加仑和野生马林的脂肪油，8种微量元素，17种氨基酸以及维生素C的含量进行测定得出：黑加仑脂肪油含量为17．9％，马林的脂肪油含量为22．3％，其中，黑加仑脂肪油中，r－亚麻酸的含量为19．02％，而马林中，其含量为9．40％，黑加仑中K，Na,Ca,Cu,Zn,Fe的含量比马林中的含量高，而Mn,Mg元素的含量却比马林含量低；马林的维生素C含量为16．22mg/g，黑加仑的含量为108mg/g，黑加仑的氨基酸的总量为1．63％，马林为1．14％。     

内蒙古土默特旗科达穗及种子化石研究

对发现于内蒙古土默特旗上石炭统一下二叠统的几种科达穗化石及种子类化石进行了研究,经鉴定确认其中有2个为新种,分别定名为长爪科达穗Cordaitanthuslongibracteatussp.nov.和多泡石籽Car polithusmultibullatussp.nov..这些珍贵的繁殖器官的发现,表明晚石炭世一早二叠世种子演化已达相当水平,对于研究科达类的演化过程具有重要的研究价值.     

Seeding and the Non-Hydrolytic Sol-Gel Synthesis of ZrW2O8 and ZrMo2O8

The unseeded non-hydrolytic sol-gel synthesis of ZrW₂O₈ and ZrMo₂O₈ produces trigonal ZrM₂O₈ (M = W, Mo) at 740 and 300–400°C, respectively. Cubic ZrW₂O₈ can be prepared using non-hydrolytic sol-gel methods by seeding with small amounts of preprepared cubic material, and the formation of the trigonal polymorph can be suppressed completely. Seeds with a small particle size are necessary for the preparation of cubic ZrW₂O₈. In contrast, seeding of ZrMo₂O₈ gels with either cubic ZrMo₂O₈ or cubic ZrW₂O₈ only lowers the temperature at which the trigonal phase crystallizes.     

杂交玉米酯酶电泳指纹的研究

本文运用聚丙烯酰胺凝胶电泳技术,以杂交玉米种胚为材料,研究制作了八个杂交种及其亲本自交系原种的种胚酯酶电泳指纹,其具有稳定、清晰、特异性强等特点．用其中的丹玉１３（Ｍｏ１７Ｈｔ×Ｅ２８）杂交组合,比较了用电泳指纹法与田间种植鉴定法．经检验人为掺混种子批中母本自交粒比率中的准确度,结果表明：指纹法与实际掺混水平更为接近,比田间种植鉴定的成熟期鉴定结果还要准确     

《大连地区植物志》补遗

对《大连地区植物志》未记载的植物种加以补充,因篇幅有限,只能以名录的形式出现。增加了１３９种,３９变种,１４变型,共１９２种。     

河南伏牛山蕨类植物区系研究

本文报道了伏牛山蕨类植物区系４个特征：（１）此区系是泛北极植物区系的一部分,具温带性质,有暖温带半湿润区向亚热带显润区过渡交替的特征;（２）此蕨类植物区系的起源古老,在系统发育或进化关系上存在着比较连贯的关系;（３）特有成分丰富;（４）是中国——喜马拉雅和中国——日本分布中心的一部分．     

南瓜籽烘烤前后化学成分的分析

对烘烤前后南瓜籽中的化学成分进行分析并对比。采用同时蒸馏萃取装置萃取南瓜籽中的挥发性成分,采取超临界CO2萃取技术萃取南瓜籽油脂,并将其分为酸、碱、中性三个部分,用气相色谱-质谱联用方法分析其中化学成分并进行对比。结果表明,南瓜籽挥发性成分中含有多种醛类和酯类化合物,烘烤后产生了大量的烷基吡嗪,其在碱性部分中的相对含量比烘烤前提高14倍多,不饱和醛类化合物含量也有明显提高。南瓜籽油脂中的主要化学成分是油酸、亚油酸及其酯类。还含有生物活性功能成分如植物甾醇、角鲨烯和维生素E等。烘烤后除角鲨烯含量有所降低,维生素E、植物甾醇、亚麻酸等均有提高。     

Synthetic process to control the total size and component distribution of multilayer magnetic composite particles

A new synthetic process to prepare composite particles with multilayers, comprised of usual polymer latices, ultra-fine magnetic particles, and a polystyrene layer was examined under various solution conditions.First, the synthetic conditions of heterocoagulates, consisted of polystyrene latices (2a=180900 nm) and NiO·ZnO·Fe₂O₃ particles (2a=20 nm), were investigated as a function of medium pH, particle concentration, and particle size ratio, based on the concept of the heterocoagulation theory as applied by Harding et al. Regular heterocoagulates were generated under suitable medium and mixing conditions, and that their total size can be controlled by selecting the size of the original polymer latices used as the core.Second, the best encapsulation condition of the heterocoagulates via emulsion polymerization with polystyrene monomer was surveyed. The encapsulation of the heterocoagulates was greatly promoted by pretreatment with oleate molecules, although there is no tendency for the encapsulation when the surfactant-free bare heterocoagulates are used as the core.