全文获取类型
收费全文 | 4361篇 |
免费 | 248篇 |
国内免费 | 199篇 |
专业分类
化学 | 1902篇 |
晶体学 | 12篇 |
力学 | 118篇 |
综合类 | 28篇 |
数学 | 534篇 |
物理学 | 661篇 |
综合类 | 1553篇 |
出版年
2024年 | 14篇 |
2023年 | 57篇 |
2022年 | 126篇 |
2021年 | 145篇 |
2020年 | 141篇 |
2019年 | 99篇 |
2018年 | 111篇 |
2017年 | 145篇 |
2016年 | 141篇 |
2015年 | 123篇 |
2014年 | 194篇 |
2013年 | 257篇 |
2012年 | 244篇 |
2011年 | 274篇 |
2010年 | 153篇 |
2009年 | 230篇 |
2008年 | 207篇 |
2007年 | 293篇 |
2006年 | 248篇 |
2005年 | 203篇 |
2004年 | 169篇 |
2003年 | 135篇 |
2002年 | 115篇 |
2001年 | 117篇 |
2000年 | 95篇 |
1999年 | 93篇 |
1998年 | 84篇 |
1997年 | 65篇 |
1996年 | 68篇 |
1995年 | 54篇 |
1994年 | 59篇 |
1993年 | 55篇 |
1992年 | 46篇 |
1991年 | 49篇 |
1990年 | 31篇 |
1989年 | 38篇 |
1988年 | 40篇 |
1987年 | 15篇 |
1986年 | 9篇 |
1985年 | 9篇 |
1984年 | 13篇 |
1983年 | 5篇 |
1982年 | 11篇 |
1981年 | 5篇 |
1980年 | 6篇 |
1979年 | 7篇 |
1978年 | 3篇 |
1976年 | 4篇 |
1974年 | 1篇 |
1973年 | 1篇 |
排序方式: 共有4808条查询结果,搜索用时 109 毫秒
1.
2.
Xinghua Li Yuqin Yang Junjie Miao Zhendong Yin Yijing Zhai Hongmei Shi Zengning Li 《Electrophoresis》2020,41(18-19):1584-1591
In the present research, field-amplified sample injection–CZE (FASI–CZE) coupled with a diode array detector was established to determine trace level sulfa antibiotic. Sulfathiazole, sulfadiazine, sulfamethazine, sulfadimethoxine, sulfamethoxazole, and sulfisoxazole were selected as analytes for the experiments. The background electrolyte solution consisted of 70.0 mmol/L borax and 60.0 mmol/L boric acid (including 10% methanol, pH 9.1). The plug was 2.5 mmol/L borax, which was injected into the capillary at a pressure of 0.5 psi for 5 s. Then the sample was injected into the capillary at an injection voltage of –10 kV for 20 s. The electrophoretic separation was carried out under a voltage of +19 kV. The capillary temperature was maintained at 20˚C throughout the analysis, and six sulfonamides were completely separated within 35 min. Compared with pressure injection-CZE, the sensitivity of FASI-CZE was increased by 6.25–10.0 times, and the LODs were reduced from 0.2–0.5 to 0.02–0.05 μg/mL. The method was applied to the determination of sulfonamides in river water and particulate matter samples. The recoveries were 78.59–106.59%. The intraday and interday precisions were 2.89–7.35% and 2.77–7.09%, respectively. This provides a simpler and faster method for the analysis of sulfa antibiotic residues in environmental samples. 相似文献
3.
郭艳红 《江西科技师范学院学报》2003,(1):62-63,78
高等职业教育以能力为本位,培养面向生产、建设、管理及服务一线的高级技术型应用人才。其培养目标、培养模式应始终坚持为经济发展建设服务,依托于经济,服务于经济,服务于社会。 相似文献
4.
序列模式挖掘是数据挖掘的重要分支,GSP算法与PSP算法是序列模式挖掘中的两种典型算法。本文介绍了这两种算法并对其进行了分析与比较。 相似文献
5.
Resistivity-temperature characteristics of sol gel YBa2Cu3Oy samples synthesized in flowing oxygen atmosphere
下载免费PDF全文
![点击此处可从《中国物理》网站下载免费的PDF全文](/ch/ext_images/free.gif)
The relationship of resistivity versus synthesizing temperature of sol gel YBa_2Cu_3O_y samples was studied when prepared under flowing oxygen conditions. A set of high-temperature ρ-T curves was obtained for the whole process. After the sample finished the test measuring, its resistivity was ρ_{300}=9.83×10^{-3 }Ω·cm at room temperature. The ρ-T curve also showed that the orthorhombic-tetragonal phase transformation of sol-gel YBa_2Cu_3O_y sample occurred at 581℃ for the sample in the rising temperature process, but at 613℃ in the cooling process, lower than that of the samples made by using the conventional powder metallurgy methods. 相似文献
6.
Tereza C. R. dos Santos Ricardo Q. Aucélio Reinaldo C. Campos 《Mikrochimica acta》2003,142(1-2):63-66
A simple and direct spectrofluorimetric method has been developed for the determination of aluminum using alizarin red PS
(1,2,4-trihydroxy 9,10-anthraquinone-3-sulfonic acid). The method is based on the strong fluorescence (480/564 nm) of Al3+ and alizarin red. Experimental parameters such as pH, concentration of the ligand, ionic strength of the solution, reaction
time and temperature were optimized in order to maximize the analytical signal. Interferences of several ions (anions and
cations) were studied and evaluated. The linear range of the method extends from 3 to 100 μg L−1. Limit of detection (3sb) was 0.9 μg L−1. The method was tested with a silicate certified reference material. Interferences were eliminated by a liquid extraction
with cupferron.
Author for correspondence. E-mail: aucelior@rdc.puc-rio.br
Received September 10, 2002; accepted January 15, 2003
Published online May 5, 2003 相似文献
7.
从生物样品中检测未知物,一直以来是毒物分析中的一个难点。如何有效地提取目标化合物,并选择适合的检测手段将未知物筛选出来,GC-MS方法是快速筛选多种毒物和药物的一个简便、可靠的手段。随着MS技术的不断发展,更灵敏、更准确的特性将使其成为药物和毒物分析中必不可少的一门技术。 相似文献
8.
本文介绍事后分层技术,说明了它不仅可用于简单随机抽样,而且可以用于放回PPS抽样。给出了事后分层估计量的形式,证明了它的无编性,并给出了它在交通运输抽样调查中的应用。 相似文献
9.
10.
In this contribution we present new data resulting from the analysis of concentration patterns of mixed juvenile fragments ejected by a highly explosive volcanic eruption that occurred on Salina Island (Aeolian Islands, Italy) and our aim is to identify the fluid-dynamic regime characterizing the magma mixing process. Concentration patterns are studied by calculating the power spectrum of concentration variability along transects crossing the magma mixing structures. Results indicate that the slope of power spectrum has an average value of about −5/3, according to Kolmogorov law of turbulence, and suggest that the magma mixing process, in the studied conditions, can be approximated by considering the passive scalar mixing hypothesis in homogeneous isotropic turbulent flow. These results represent a first step towards a better understanding of magma mixing processes associated to highly explosive volcanic eruptions and this first step is taken by studying concentration patterns in volcanic rocks by coupling petrological and non-linear dynamics methods. 相似文献