首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   1257篇
  免费   52篇
  国内免费   47篇
化学   372篇
晶体学   12篇
力学   15篇
综合类   8篇
数学   1篇
物理学   92篇
综合类   856篇
  2024年   6篇
  2023年   10篇
  2022年   28篇
  2021年   18篇
  2020年   30篇
  2019年   31篇
  2018年   33篇
  2017年   40篇
  2016年   44篇
  2015年   55篇
  2014年   47篇
  2013年   64篇
  2012年   65篇
  2011年   68篇
  2010年   62篇
  2009年   69篇
  2008年   70篇
  2007年   88篇
  2006年   77篇
  2005年   67篇
  2004年   63篇
  2003年   53篇
  2002年   45篇
  2001年   29篇
  2000年   26篇
  1999年   31篇
  1998年   25篇
  1997年   20篇
  1996年   24篇
  1995年   6篇
  1994年   8篇
  1993年   12篇
  1992年   12篇
  1991年   5篇
  1990年   7篇
  1989年   10篇
  1988年   3篇
  1987年   3篇
  1985年   1篇
  1983年   1篇
排序方式: 共有1356条查询结果,搜索用时 437 毫秒
1.
动物体的鲜重(FM)、干重(DM)、灰分重(AM)及其比值在不同分类群和不同生态型的动物类群中变化很大,其中 DM/FM 和 AM/DM 比值反映了动物体水、无机矿物质和有机物三者之间的比例,是了解动物体化学组成的两个重要参数.我们在进行直翅目蝗总科昆虫整体痕量元素含量分析的同时,测定和计算了35种蝗总科昆虫的AM/DM 比值,现将结果以及其它主要动植物类群的有关资料一并介绍如下.  相似文献   
2.
唐宋时期峡江地区“击鼓焚山”的民俗活动是远古时代尚巫之风的残存,其目的是为烧龙祈雨以禳除旱灾;而“烧畬下种”则是自远古“刀耕火种”传承下来的一门农耕技术,但由于“占卜伺雨”的仪式亦使它带上了一些巫风色彩。二者既有明显的区别又有一定的联系。  相似文献   
3.
介绍了塑烧板除尘器的系统总体结构和工作原理,阐述了模糊控制模型的建立。  相似文献   
4.
Two series of size‐fractionated combusted residues, a bag‐house ash and a scrubber residue, from a municipal solid waste incinerator (MSWI) were prepared and extracted by means of sequential chemical extraction (SCE) procedures proposed by Tessier. Concentrations of water‐soluble phase, exchangeable phase, carbonated phase, Fe/Mn oxide phase, organic matter phase, and residual phase bound amphoteric metals (Pb and Zn) were obtained, and have been compared with those of single batch extraction of toxic characteristic leaching procedure (TCLP). In each size fraction of baghouse ash or scrubber residue, lead or zinc shows a common phenomena that the TCLP value is always lower than the content of the water‐soluble fraction. For lead, baghouse ash has a significant size‐dependent distribution on the water‐soluble phase to perform a size‐dependent test of lead in the TCLP test. The zinc TCLP data having less size dependence might be due to that neither the baghouse ash nor the scrubber residue has a size‐dependent distribution on the water‐soluble zinc phase.  相似文献   
5.
Fly ash samples of cement works were analysed using slurry nebulization inductively coupled plasma atomic emission spectrometric (ICP-AES). Because of the influence of the experimental factors on the signal intensity, the optimal conditions of the analysis circumstances were determined. Control analyses (wet digestion followed by ICP-AES, and XRF of dry powders (pressed pellets)) were also carried out to compare the results. Based on the result, it was concluded that the slurry nebulization method using slurry standard of same type reference material for calibration can be applied for rapid but less precise (RSD 5–10%) determination of the elements in fly ash.  相似文献   
6.
Incineration methods are becoming increasingly important from the view point of the need to minimize the environmental impact of waste tyre disposal. Combustion of waste tyre, one high ash coal and tyre-coal blends with 10, 30 and 50% waste tyre were investigated by means of thermogravimetric analysis (TGA) carried out at 20 K min−1 in the temperature range from ambient temperature to 1273 K. And effects of the mixed proportion between coal and waste tyre on the combustion process, ignition and burnout characteristics were also studied. The results indicate that the combustion of waste tyre is controlled by the emission of volatile matter, the regions are more complex for waste tyre (three or more peaks) than for coal (one peak). Also as compared with the case of burning only high ash coal, the incorporation of waste tyre can improve the combustion characteristics of high ash coal, especially the ignition performance and the peak weight loss compared with the separate burning of waste tyre and coal. Moreover, comparisons of the TG-DTG profiles between experimental and calculational results, it is indicate that there is a comparatively important difference, the co-combustion characteristics is the coupling effect between waste tyre and coal. The data resulting also showed that the co-combustion of waste tyre and low quanlitied coal as fuel is feasible.  相似文献   
7.
粉煤灰与几种酸固相反应特性的表面分析   总被引:1,自引:0,他引:1  
用扫描电镜.能量色散谱研究了粉煤灰与酸的固相反应过程中表面形貌和化学组成变化特性。室温下粉煤灰分别与HCI、HNO3、H2SO4、HCIO4固相反应后,表面产生直径20—200nm的结晶颗粒或晶柱。反应生成的水溶物结晶体的扫描电镜图像分别呈手指状、龟背形、蛛蛛状、蝙蝠态,分别为氯化铝铁混晶、硝酸铝铁混晶、硫酸铝铁混晶和高氯酸铝铁混晶。粉煤灰是硅、铝、铁等元素的氧化物聚集体,铁铝等氧化物主要分布在颗粒表面,氧化硅主要分布在颗粒内层。用少量酸进行固相反应这些氧化物聚集体可相互剥离,用H2SO4处理粉煤灰优先将铁铝氧化物转化成可溶性硫酸盐。  相似文献   
8.
A lime-pozzolan cement was used to make pastes containing different quantities of MSW fly ash. After setting, the pastes were cured in water at room temperature from 1 h to 260 days. The hydration characteristics and the nature of the hydration products of the various pastes were studied by simultaneous TG/DSC thermal analysis and X-ray diffractometry. The MSW fly ash was found to induce a slowing of the hydration process in lime-pozzolan pastes, and after some days an evident acceleration of hydration reactions occurred. Sulphate and chloride in the MSW fly ash yield hydration products forming a cementitious matrix.The author is grateful to D. Calabrese for assistance with the thermal and XRD analyses.  相似文献   
9.
Utilization of one waste material to control pollution caused by another is of high significance in the remediation of environmental problems. Rice husk, an abundantly available agricultural waste, can be used as a low cost adsorbent for dyes and heavy metals in effluent streams. The possible utilization of rice husk ash as an adsorbent for methylene blue dye from aqueous solutions has been investigated. Ash samples from husks of two origins were prepared at different temperatures and their physical, chemical spectroscopic and morphological properties were determined. XRD, FTIR and SEM were some of the techniques adopted for the characterization. The samples were also analyzed for bulk density, pH, nitrogen adsorption properties and lime reactivity. Experiments of methylene blue adsorption on the ash samples were conducted using batch technique and a comparative study was made. Results were analyzed using linear, Langmuir and Freundlich isotherms. The values of separation factor indicate that most of the ash samples do adsorb the dye molecules, but in varying quantities. Calcination at 900C reduces the adsorption capacity of the ash to a great extent. Regression analysis shows that the experimental data fits both Langmuir and Freundlich isotherms for certain concentration limits. The adsorbate species are most probably transported from the bulk of the solution into the solid phase through intra-particle diffusion process. Kinetics of adsorption was found to follow pseudo second order rate equation with R 2∼ 0.99. The highest adsorption capacity (Q 0) achieved is found to be ∼690 mg/g, which is even higher than the values reported for activated carbon from rice husk. The adsorption capacity of the ash samples are in good agreement with their surface area and pore volume.  相似文献   
10.
在西北季节冻土区广泛分布着盐渍土,其在空间分布上连续性差,工程性质极其不稳定;且浅层盐渍土受冻融作用的反复影响,其力学性质长期处于动态的变化之中,给工程设计与建设带来了极大的挑战.鉴于此,通过压缩试验及无侧限抗压强度试验,研究稻壳灰对盐渍土的改良效果.结果表明,稻壳灰可以显著地改善盐渍土的压缩特性,并提高其无侧限抗压强度,且改良土的压缩系数与抗压强度之间呈现出负相关的线性关系.随着掺灰量和养护龄期的增加,改良土的压缩系数不断减小,无侧限抗压强度呈现出不断增加的趋势,最大可增加4倍左右.以抗压强度损失率为指标对改良土的抗冻性进行了评价,发现改良土的抗冻性随着掺灰量的增加呈现出先增强后减弱的趋势,且在15%的掺灰量时,其抗冻性效果最显著;相对而言,养护龄期对于改良土的抗冻性影响较小.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号