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1.
This review provides a comprehensive evaluation of solidified floating organic drop microextraction (SFODME) procedures for metal ions preconcentration and their contributions to green chemistry. In this article we focused on the modifications that have been performed in the recent years to improve this environmentally friendly procedure. Among the most important of these modifications are the inclusion of ultrasonic energy, vortex and air agitation to enhance the dispersion process. The article also discussed new challenges in the procedure by using more ecofriendly solvents as extractants such as ionic liquids, deep eutectic. and supramolecular solvents. The coupling of SFODME with solid phase extraction increases selectivity and efficiency of the preconcentration procedure.  相似文献   
2.
Because of its unpredictable side effects and efficacy, the anticancer drug docetaxel (DTX) requires improved characterisation of its pharmacokinetic profiles through population pharmacokinetic studies. A sensitive and rugged LC–MS/MS method for the detection of DTX in human plasma was developed and optimised using paclitaxel as an internal standard (IS). The plasma samples underwent rapid extraction using hybrid solid-phase extraction-protein precipitation. The analyte and IS were separated with an isocratic system on a Zorbax Eclipse Plus C18 column using water containing 0.05% acetic acid along with 20 μM of sodium acetate and methanol (30/70, v/v) as the mobile phase. Quantification was performed using a triple quadrupole mass spectrometer through multiple reaction monitoring in positive mode, using the m/z 830.3 → 548.8 and m/z 876.3 → 307.7 transitions for DTX and paclitaxel, respectively. The range of the calibration curve was 1–500 ng/mL for DTX, and the linear correlation coefficient was >0.99. The accuracies ranged from −4.6 to 4.2%, and the precision was no higher than 7.0% for the analytes. No significant matrix effect was observed. Both DTX and the IS showed considerable recovery. This method was finally applied to the establishment of a population pharmacokinetic model to optimise the clinical use of DTX.  相似文献   
3.
城乡人口差异是导致城乡贫富差距的重要根源,解决城乡贫富差距问题应该逐渐降低农村人口比例、提高农村人口素质。  相似文献   
4.
A carousel is a dynamical system that describes the movement of an equilateral linkage in which the midpoint of each rod travels parallel to it. They are closely related to the floating body problem. We prove, using the work of Auerbach, that any figure that floats in equilibrium in every position is drawn by a carousel. Of special interest are such figures with rational perimetral density of the floating chords, which are then drawn by carousels. In particular, we prove that for some perimetral densities the only such figure is the circle, as the problem suggests.  相似文献   
5.
小麦群体连续选择效应的综合分析   总被引:1,自引:1,他引:0  
本试验对由信谷核不育基因构成的异效群体内4个性状进行连续两轮歧化选择,并将所得数据进行群体综合分析。结果表明:整个群体的平均表现和变异程度未发明显变化;但群体分布状况有一定改变,尤其是每穗粒数的分布数化较为明显;株高和千粒重的有效因子数估计基本符合小麦遗传实际表现,每穗粒数的有效有效因子数估计略低,说明此性状遗传背景较为简单。  相似文献   
6.
ABSTRACT. Predator‐prey relationships account for an important part of all interactions betweenspecies. In this paper we provide a microfoundation for such predator‐prey relations in afood chain. Basic entities of our analysis are representative organisms of species modeled similar to economic households. With prices as indicators of scarcity, organisms are assumed to behave as if they maximize their net biomass subject to constraints which express the organisms' risk of being preyed upon during predation. Like consumers, organisms face a ‘budget constraint’ requiring their expenditure on prey biomass not to exceed their revenue from supplying own biomass. Short‐run ecosystem equilibria are defined and derived. The net biomass acquired by the representative organism in the short term determines the positive or negative population growth. Moving short‐run equilibria constitute the dynamics of the predator‐prey relations that are characterized in numerical analysis. The population dynamics derived here turn out to differ significantly from those assumed in the standard Lotka‐Volterra model.  相似文献   
7.
建立并分析了一类非线性生育率阶段结构的单种群的收获模型,得到了正平衡点全局稳定的条件,给出了最优收获策略.  相似文献   
8.
The problem of surface wave diffraction on a floating elastic plate is considered. The relation between the parameters of the elastic vibrations of the plate and the transmitted and reflected wave amplitudes is investigated. It is shown that the maximum amplitudes of the plate stresses and deflections depend nonmonotonically on the incident wave frequency and are reached simultaneously with the maxima of both the transmission coefficient and the length of the wave penetrating into the plate. This makes it possible to use the transmission coefficient as a parameter for investigating the maximum and minimum amplitudes of the hydroelastic vibrations of the plate. As an example, this criterion is used to minimize the vibrations of a plate whose leading edge is elastically connected to the bottom.  相似文献   
9.
In this paper, stochastic age-dependent population equations with Poisson jumps are considered. In general, most of stochastic age-dependent population equations with jumps do not have explicit solutions, thus numerical approximation schemes are invaluable tools for exploring their properties. The main purpose of this paper is to develop a numerical Euler scheme and show the convergence of the numerical approximation solution to the true solution.  相似文献   
10.
李健全  陈任昭 《应用数学》2006,19(4):673-682
讨论了一类非线性时变种群扩散系统的最优分布控制问题,利用LionsJL的偏微控制理论和先验估计,证明了系统最优分布控制的存在性.所得结果可为非线性种群扩散系统中的最优控制问题的实际研究提供必要的理论基础.  相似文献   
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