全文获取类型
收费全文 | 788篇 |
免费 | 63篇 |
国内免费 | 50篇 |
专业分类
化学 | 240篇 |
晶体学 | 3篇 |
力学 | 14篇 |
综合类 | 5篇 |
数学 | 6篇 |
物理学 | 28篇 |
综合类 | 605篇 |
出版年
2023年 | 10篇 |
2022年 | 21篇 |
2021年 | 25篇 |
2020年 | 26篇 |
2019年 | 18篇 |
2018年 | 20篇 |
2017年 | 28篇 |
2016年 | 31篇 |
2015年 | 40篇 |
2014年 | 43篇 |
2013年 | 45篇 |
2012年 | 48篇 |
2011年 | 41篇 |
2010年 | 26篇 |
2009年 | 40篇 |
2008年 | 39篇 |
2007年 | 43篇 |
2006年 | 41篇 |
2005年 | 46篇 |
2004年 | 28篇 |
2003年 | 30篇 |
2002年 | 21篇 |
2001年 | 19篇 |
2000年 | 18篇 |
1999年 | 15篇 |
1998年 | 18篇 |
1997年 | 8篇 |
1996年 | 15篇 |
1995年 | 14篇 |
1994年 | 12篇 |
1993年 | 13篇 |
1992年 | 7篇 |
1991年 | 9篇 |
1990年 | 10篇 |
1989年 | 6篇 |
1988年 | 10篇 |
1987年 | 9篇 |
1986年 | 5篇 |
1985年 | 1篇 |
1983年 | 2篇 |
排序方式: 共有901条查询结果,搜索用时 15 毫秒
1.
Hydrodynamic cavitation experiments in microfluidic systems have been performed with an aqueous solution of luminol as the working fluid. In order to identify where and how much reactive radical species are formed by the violent bubble collapse, the resulting chemiluminescent oxidation reaction of luminol was scrutinized downstream of a constriction in the microchannel. An original method was developed in order to map the intensity of chemiluminescence emitted from the micro-flow, allowing us to localize the region where radicals are produced. Time averaged void fraction measurements performed by laser induced fluorescence experiments were also used to determine the cavitation cloud position. The combination void fraction and chemiluminescence two-dimensional mapping demonstrated that the maximum chemiluminescent intensity area was found just downstream of the cavitation clouds. Furthermore, the radical yield can be obtained with our single photon counting technique. The maximum radical production rates of 1.2*107 OH/s and radical production per processed liquid volume of 2.15*1010 HO/l were observed. The proposed technique allows for two-dimensional characterisation of radical production in the microfluidic flow and could be a quick, non-intrusive way to optimise hydrodynamic cavitation reactor design and operating parameters, leading to enhancements in wastewater treatments and other process intensifications. 相似文献
2.
Rhodium catalysts have been prepared on palygorskite and montmorillonite (clay) supports by reduction with hydrogen (1 atmosphere) at room temperature of a cationic organometallic rhodium compound anchored to the support. The activity of these catalysts for the hydrogenation of liquid-phase 1-hexene remains constant with increase of prehydrogenation time and with re-use for several runs. No rhodium leaching is observed. 相似文献
3.
A Raney-Ag catalyst was prepared by leaching out aluminium from a Raney Ag-Al alloy with NaOH solution. The kinetics of leaching
has been investigated in a stirred-batch-reactor at various temperatures by using alloy particles of different sizes. The
kinetic model best fitting the experimental results has been determined.
This revised version was published online in June 2006 with corrections to the Cover Date. 相似文献
4.
目前实验室制备己二酸的方法大部分采用环己醇经高锰酸钾氧化来制得,这种方法所耗用的氧化剂用量大,而且所制备出的已二酸实际产率不高。我们采用环己酮为原料来制己二酸,此方法可达到较理想的效果。改进后同样能使学生掌握实验技能,达到实验教学的目的,而且也节省了资金和时间。 相似文献
5.
本文研究了贵州高硫型高品位铝土矿溶出性能,考查了石灰添加量、溶出温度、苛性碱浓度和溶出时间对氧化铝溶出率的影响以及铝土矿的硫向溶液中的转化率(即硫的溶出率)的影响;还研究了用铝酸钡净化拜耳赤泥洗液的除硫条件和效果。 相似文献
6.
刘占瑞 《河北科技师范学院学报》1991,(1)
本文就加强革命史教学中国情教育的战略意义,以及对怎样认识和把握国情,提出了一些想法。在此基础上,探讨了国情教育的基本内容和贯彻方法,来达到解决学生当前深层次认识问题的目的。 相似文献
7.
In order to enhance the
electrogenerative leaching rate of sphalerite reasonably, the basic principle
of generative process was applied to the simultaneous leaching of sphalerite
in the presence of MnO2. It was confirmed by experimental
results that both mental ions and electric energy could be obtained in the
simultaneous electrogenerative leaching process. The leaching cell had the
open circuit potential about 1.0 V, about 2000 C of electric quantity was
obtained, the optimal leaching ratio of Zn2+ and
Mn2+ was 48.5, 39.6% respectively, after electrogenerative
leaching for 11 h. 相似文献
8.
A.A. Ahmed I.M. Youssof A.F. Abbas O. Abou Eleinen 《Journal of Sol-Gel Science and Technology》1998,13(1-3):753-756
The chemical durability of lead glass tumblers (24% PbO) in a 4% (v/v) acetic acid solution before and after coating with sol-gel derived SiO2 films was assessed to determine the extent of reduction in Pb-leaching that can be achieved. It was found that by coating the internal surface of the glass tumblers with 1 ml of 10% TEOS solutions at 100°C and densifying the coating formed at 500°C for 1 h, it was possible to reduce Pb-leaching to about one quarter of that of the uncoated glass. 相似文献
9.
随着地浸采铀矿山的退役,特别是应现代绿色矿山建设的要求,地下水修复越来越被重视,如何制定酸法地浸采铀矿山地下水修复法规,采用哪种修复技术才能获得更好的效果,这些问题一直困扰着环境保护部门和项目执行者。本研究针对酸法浸出矿山特点,提出了地下水修复法规的制定原则,并实践了地下水修复综合技术、自然净化、迁移净化、冲洗、弱酸浸出等方法,并在应用中获得较好的效果。在总结地浸采铀矿山地下水修复现场试验和退役矿山实际应用的基础上,充分分析影响地下水修复的矿床自然条件、地下水质量和用途、修复技术、修复费用和时间等因素,给出了推荐的酸法地浸采铀矿山地下水修复策略。 相似文献
10.
在灌区水资源优化调度的基础上,考虑了土壤临界含盐量、土壤和地下水水盐动态等因素,提出了灌区淋洗水量优化计算方法,并给出了算例。 相似文献