全文获取类型
收费全文 | 6524篇 |
免费 | 533篇 |
国内免费 | 459篇 |
专业分类
化学 | 1108篇 |
晶体学 | 5篇 |
力学 | 515篇 |
综合类 | 56篇 |
数学 | 500篇 |
物理学 | 803篇 |
综合类 | 4529篇 |
出版年
2024年 | 35篇 |
2023年 | 102篇 |
2022年 | 205篇 |
2021年 | 172篇 |
2020年 | 165篇 |
2019年 | 161篇 |
2018年 | 156篇 |
2017年 | 206篇 |
2016年 | 203篇 |
2015年 | 212篇 |
2014年 | 342篇 |
2013年 | 362篇 |
2012年 | 408篇 |
2011年 | 404篇 |
2010年 | 311篇 |
2009年 | 377篇 |
2008年 | 368篇 |
2007年 | 421篇 |
2006年 | 371篇 |
2005年 | 340篇 |
2004年 | 334篇 |
2003年 | 223篇 |
2002年 | 207篇 |
2001年 | 170篇 |
2000年 | 156篇 |
1999年 | 143篇 |
1998年 | 117篇 |
1997年 | 93篇 |
1996年 | 108篇 |
1995年 | 106篇 |
1994年 | 92篇 |
1993年 | 75篇 |
1992年 | 69篇 |
1991年 | 45篇 |
1990年 | 56篇 |
1989年 | 52篇 |
1988年 | 48篇 |
1987年 | 35篇 |
1986年 | 23篇 |
1985年 | 11篇 |
1984年 | 9篇 |
1983年 | 1篇 |
1982年 | 4篇 |
1981年 | 5篇 |
1980年 | 1篇 |
1979年 | 3篇 |
1978年 | 1篇 |
1977年 | 3篇 |
1974年 | 1篇 |
1955年 | 4篇 |
排序方式: 共有7516条查询结果,搜索用时 0 毫秒
1.
疏松砂岩油藏在长期注水开发过程中,往往伴随着大孔道的出现,这严重影响了油藏水驱开发效果,制约了采出程度的进一步提高,因此,大孔道识别及有效封堵成为该类油藏急需解决的关键问题.通过研究分析,确定了影响大孔道从形成到发展的7种主要静态因素,以及标志大孔道形成的6种主要动态因素.将层次分析法及灰色关联法相结合,分别计算静态及动态因素的权重,建立了全新的大孔道定性识别模型.示踪剂监测结果验证了该方法的实用性和有效性. 相似文献
2.
Studies on metabolism of total glucosides of paeony from Paeoniae Radix Alba in rats by UPLC‐Q‐TOF‐MS/MS 下载免费PDF全文
Wenli Cao Xinguo Wang Haojie Li Xuliang Shi Wencheng Fan Shaohua Zhao Minyan Liu Liying Niu 《Biomedical chromatography : BMC》2015,29(11):1769-1779
Total glucosides of paeony are the active constituents of Paeoniae Radix Alba. In this study, a novel strategy was proposed to find more metabolites and the differences between paeoniflorin, albiflorin and total glucosides of paeony (TGP). This strategy was characterized as follows: firstly, the animals were divided into three groups (paeoniflorin, albiflorin and TGP) to identify the source of TGP metabolites from paeoniflorin or albiflorin; secondly, a generic information‐dependent acquisition scan for the low‐level metabolites was triggered by the multiple mass defect filter and dynamic background subtraction; thirdly, the metabolites were identified with a combination of data‐processing methods including mass defect filtering, neutral loss filtering and product ion filtering; finally, a comparative study was used in the metabolism of paeoniflorin, albiflorin and TGP. Based on the strategy, 18 metabolites of TGP, 10 metabolites of paeoniflorin and 13 metabolites of albiflorin were identified respectively. The results indicated that the hydrolysis, conjugation reaction and oxidization were the major metabolic pathways, and the metabolic sites were the glycosidic linkage, the ester bond and the benzene ring. This study is first to explore the metabolism of TGP, and these findings enhance our understanding of the metabolism and the interactions of paeoniflrin and albiflorin in TGP. Copyright © 2015 John Wiley & Sons, Ltd. 相似文献
3.
详细介绍了双光头同步控制原理.对采集的伺服模块聚焦误差跟踪信号及共焦模块读写光头的聚焦线圈驱动信号进行了频域分析,并以此两路信号作为系统输入输出,分别对三种参数模型进行参数优化.根据3种模型的频率响应及阶跃响应,选择双光头同步控制过程的参数模型为[450]阶的ARX模型.实测曲线与模型仿真结果符合度(fit)为78.0259%. 相似文献
4.
A stochastic approximation algorithm for estimating multichannel coefficients is proposed, and the estimate is proved to converge to the true parameters a.s. up-to a constant scaling factor. The estimate is updated after receiving each new observation, so the output data need not be collected in advance. The input signal is allowed to be dependent and the observation is allowed to be corrupted by noise, but no noise statistics are used in the estimation algorithm. 相似文献
5.
对吉林文史出版社1999年版《小窗幽记》译文简注的曲解谬误之处,逐条或作辨正,或为补缺。举凡译文的曲解、标点的讹错、人物典故的误植或缺注等处,皆尽可能予以更正或补充。作为古籍的普及本,应尽可能避免将错误的知识传播给广大受众。 相似文献
6.
T. Beda 《Journal of Polymer Science.Polymer Physics》2007,45(13):1713-1732
A constitutive phenomenological model completing the Gent‐Thomas concept is carried out to formulate laws governing the hyperelastic behavior of incompressible rubber materials. It is shown that the phenomenological Gent‐Thomas model (1958) and the constrained chain model (1992) give similar precise results at small to moderate deformation. On the other hand, comparisons of the outcome of the proposed model with that of the molecular model from the combined concepts of Flory‐Erman and Boyce‐Arruda (2000), and with those of the phenomenological models of Ogden (1982), Yeoh‐Fleming (1997), Pucci‐Saccomandi (2002) and Beda (2005) are made. Residual inconveniences raised by attractive continuum models in rubber elasticity literature have been successfully overcome. Results from both the statistical and phenomenological mechanics concepts are compared with the data of some useful classical materials (rubbers of Treloar, Rivlin‐Saunders, Pak‐Flory and Yeoh‐Fleming). The results permit one to see salient equivalence of the two theories for a more reliable prediction of stress‐stretch response for all states of any mode of deformation. A complete and exhaustive analysis of the Mooney plot that combines small and very large extension‐compression has been quite essential in assessing the validity of models. A method of identification of material parameters is presented and data of the simple tension suffice for the determination of the parameter values. It is shown that the ordinary identification procedures, such as the usual least squares, a very much used numerical method in materials investigation, can be unsuitable in some cases of hyperelastic modeling. © 2007 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 45: 1713–1732, 2007 相似文献
7.
化学分析在火灾原因技术鉴定中的应用 总被引:1,自引:0,他引:1
梁雄松 《广西民族大学学报》2002,8(4):48-50
采用化学分析方法对火灾现场中的微量油品、特殊物质和混凝土等痕迹物证的化学分析鉴定,对火灾原因和火灾责任的认定起关键作用. 相似文献
8.
Auguet C. Martorell F. Moll F. Torra V: 《Journal of Thermal Analysis and Calorimetry》2002,70(1):277-290
The miniaturized calorimetric devices furnish a reduced working flat surface and permits measurements with extremely low-mass
quantities. The experimental sensitivity shows relevant position dependence with x-y surface coordinates and with z-distance. The device identification is realized via a 2-D model based in Fourier general equation.
Using the Marquardt method the experimental flat surface device can be identified and the fitted parameters used to simulate
the behavior of the experimental system. From the model, the effects of several dissipation configurations can be evaluated.
Also, via the RC-analogy, a way to 3-D experimental devices is roughly described.
This revised version was published online in July 2006 with corrections to the Cover Date. 相似文献
9.
We present a Bayesian theory of object identification. Here, identifying an object means selecting a particular observation from a group of observations (variants), this observation (the regular variant) being characterized by a distributional model. In this sense, object identification means assigning a given model to one of several observations. Often, it is the statistical model of the regular variant, only, that is known. We study an estimator which relies essentially on this model and not on the characteristics of the “irregular” variants. In particular, we investigate under what conditions this variant selector is optimal. It turns out that there is a close relationship with exchangeability and Markovian reversibility. We finally apply our theory to the case of irregular variants generated from the regular variant by a Gaussian linear model. 相似文献
10.
Philippe Quevauviller Rob Ritsema Roberto Morabito Wilfried M. R. Dirkx Salvatore Chiavarini Jos M. Bayona Olivier F. X. Donard 《应用有机金属化学》1994,8(6):541-549
Biogeochemical pathways of tin species in the environment are still controversial, e.g. with regard to methylation and transmethylation phenomena, owing to the fact that the identification of methylated tin-compounds is often difficult. The previous tentative identification of a mixed methylbutyltin compound in sediment and biological samples by GC/AAS after hydride generation gave an illustration of this problem. This compound was previously identified in sediments by other authors and also suspected to occur in a contaminated sediment sample from the Boyardville Marina, France. The retention time obtained by GC/AAS corresponded to the actual retention time of a mixed methylbutyltin calibrant. However, additional checks demonstrated that the compound detected was actually monophenyltin. This evidence was produced by a thorough analysis of a selected sediment sample by alternative techniques such as GC/AAS and GC/AES after pentylation, GC/FPD and GC/MS. The results presented highlight the need for a full identification of compounds to avoid mis-interpretation. 相似文献