Gelation of poly(n-butylisocyanate) in benzene

Poly (n-butylisocyanate)-benzene solutions prepared by solubilization at 45°C, followed by aging at room temperature were found to be metastable for months, although, eventually, they separated into a birefringent polymer-rich phase and an isotropic solution. These metastable solutions, as well as isothermally phase-separated biphasic samples, flowed and exhibited dynamic moduli indicative of low polymer connectivity. By contrast samples prepared by a freeze-thaw cycle were uniformly and highly birefringent and showed network (gel) behavior at room temperature. The mechanism of gel formation is most likely the exclusion of the polymer from the benzene crystal during crystallization, forcing the polymer to align and exist at grain boundaries. Films formed from solutions have different moduli than those formed from gels, and are consistent with the proposed mechanism.     

复合式鱼雷战斗部威力试验研究

该文分析了复合式鱼雷战斗部的结构和性能，结合模拟威力试验，验证了利用复合式鱼雷战斗部攻击抗爆能力强的大、中型潜艇的可行性，并提出了增强威力的具体措施，为进一步指导复合式鱼雷战斗部设计提供参考。     

幂律流体绕流楔形物体时的层流边界层

从流体力学和非牛顿流体力学的基本方程出发，在未作任何假设的情况下，通过引入合理的相似变量，得出了幂律流体绕流楔形物体时的层流边界层常微分方程及其数值解，该常微分方程及其解在塑性指数ｎ＝１时，与经典流体力学中的方程及解完全相同。     

明代复古主义诗学诸理论及发展

明代复古主义由祈向诗歌美学高境，而推崇汉唐，讲求格调，在展示独特理论魅力的同时，何景明重视才情，已对其先天弱点有所修正；而面对明中叶新思潮的挑战，王世贞吸收作家才思真情自我个性等方面的内涵，突破固有的理论局限；胡应麟发掘兴象风神等汉唐诗歌品质，补充体格声调理论之不足；许学夷突出从“体”的中偏正变的历史考察、尤其各种“变”的环节与样态中，探求和分辨诗歌本乎天成、形迹俱融、风神超迈的根本性质。从而使复古主义成为一种突出诗歌内在特性研究而又比较圆融的诗学理论。     

原位颗粒含量对半固态7075铝合金组织的影响

制备具有不同原位TiC颗粒含量的喷射沉积7075铝合金,在610℃和620℃进行二次加热并保温30min,淬火固定半固态组织.采用扫描电镜观察其组织,利用平均截线法统计其晶粒尺寸,分析不同颗粒含量对喷射沉积7075铝合金半固态组织的影响规律.结果表明:当TiC颗粒含量达到2.91%(体积分数)时已经产生良好的钉扎效果,使得合金基本保持喷射沉积组织特征,能够满足后续的半固态成形工艺要求;TiC颗粒含量超过2.91%后,晶粒尺寸会进一步减小,但晶界上的颗粒明显增多并呈网状分布;TiC颗粒含量小于2.91%时,局部区域发生晶粒的异常长大现象,使合金组织的均匀化程度下降.     

侵彻弹体快速烤燃安全特性实验研究

为了考核大尺寸侵彻弹体的快速烤燃安全特性,利用自行研制的快速烤燃装置开展了实验。将质量为290 kg的侵彻弹体平吊在距航空燃油液面0.4 m的高度进行快速加热,实时采集弹体表面温度并拍摄实验过程,同时测量距弹体质心水平7 m处的反射冲击波超压,最后从加热时间、弹体表面温度、实验后现场破坏情况、反射冲击波超压峰值、反应机理及响应类型等方面对大尺寸侵彻弹体的快速烤燃安全特性进行了详细分析。实验结果表明：侵彻弹体在537 ℃高温中加热16 min 4 s后开始发生剧烈反应,且弹体内腔下方炸药最先响应形成热点,逐渐积聚的高温高压气体将壳体撕裂后快速泄压,在7 m处测量得到的反射冲击波超压峰值为33.622 kPa,远小于该弹体在空气中完全爆轰产生的冲击波超压峰值。综合判断该侵彻弹体的快速烤燃响应类型为爆燃,其安全特性满足要求。

     

带尾翼EFP形成的三维数值模拟研究

带尾翼的杆状爆炸成形侵彻体(explosively formed penetrator,简称EFP)具有良好的飞行稳定性和侵彻性能.在对能形成该种类型EFP的战斗部结构形式进行分析的基础上,以两种典型的结构形式(异形壳体和多点起爆)为例,采用AUTODYN-3D软件进行了EFP成形的三维数值模拟,得到了尾部带有不同形状尾翼的爆炸成形侵彻体.计算结果对于EFP战斗部的设计具有重要的参考价值.     

Synthesis process of Ba-ferrites from α-FeOOH and γ-FeOOH and investigation of magnetic properties

The claviform BaFe₁₂O₁₉ crystals were synthesized by the precipitation-toptactic reaction method using α-FeOOH and γ-FeOOH as raw materials respectively. The synthesis processes of BaFe₁₂O₁₉, studied by XRD, SEM, EDS, FT-IR, and TG-DTA techniques, included preparations of precursor γ and precursor α, formations of α-Fe₂O₃ and BaFe₂O₄, and production of rod-like BaFe₁₂O₁₉ through dehydroxylation of pod-like FeOOH, followed by reactions of α-Fe₂O₃ with BaCO₃ and BaFe₂O₄. The crystallinity of α-Fe₂O₃ and BaCO₃ from precursor α was better than from precursor γ due to the direct dehydroxylation of α-FeOOH, resulting in a lower nucleation rate and better crystallinity of BaFe₂O₄. BaFe₁₂O₁₉ prepared from precursor α showed lower crystallinity and purity with a higher length-diameter ratio than from precursor γ. The VSM results proved that the appearance of final products had an important influence on magnetic properties.     

木质褐煤制定型活性炭对粉煤的粒度要求

以木质褐煤制活性炭为例，探讨了粉煤粒度及粒度组成对活性炭性能的影响．得出了以木质褐煤为原料制备定型活性炭用粉煤的最佳粒度和粒度组成。     

铁山岩体地球化学特征及其找矿意义

通过长期的野外调查所掌握的地质资料和分析数据，从定性、定量上研究铁山岩体的地球化学特征．所论证的地球化学特征又恰好与岩体赋存的矿床的时空分布相吻合。从而揭示了岩体地球化学特征的找矿意义。