全文获取类型
收费全文 | 33984篇 |
免费 | 2564篇 |
国内免费 | 2099篇 |
专业分类
化学 | 3549篇 |
晶体学 | 320篇 |
力学 | 1692篇 |
综合类 | 311篇 |
数学 | 5159篇 |
物理学 | 6944篇 |
综合类 | 20672篇 |
出版年
2024年 | 79篇 |
2023年 | 239篇 |
2022年 | 505篇 |
2021年 | 602篇 |
2020年 | 636篇 |
2019年 | 633篇 |
2018年 | 644篇 |
2017年 | 918篇 |
2016年 | 897篇 |
2015年 | 988篇 |
2014年 | 1689篇 |
2013年 | 2198篇 |
2012年 | 1846篇 |
2011年 | 1964篇 |
2010年 | 1603篇 |
2009年 | 1824篇 |
2008年 | 1832篇 |
2007年 | 2474篇 |
2006年 | 2171篇 |
2005年 | 1879篇 |
2004年 | 1731篇 |
2003年 | 1599篇 |
2002年 | 1341篇 |
2001年 | 1080篇 |
2000年 | 1006篇 |
1999年 | 913篇 |
1998年 | 737篇 |
1997年 | 674篇 |
1996年 | 649篇 |
1995年 | 542篇 |
1994年 | 489篇 |
1993年 | 385篇 |
1992年 | 365篇 |
1991年 | 281篇 |
1990年 | 245篇 |
1989年 | 221篇 |
1988年 | 161篇 |
1987年 | 142篇 |
1986年 | 79篇 |
1985年 | 97篇 |
1984年 | 81篇 |
1983年 | 63篇 |
1982年 | 46篇 |
1981年 | 22篇 |
1979年 | 13篇 |
1978年 | 12篇 |
1977年 | 14篇 |
1976年 | 10篇 |
1974年 | 8篇 |
1955年 | 5篇 |
排序方式: 共有10000条查询结果,搜索用时 85 毫秒
1.
D-S证据理论可应用于多源数据融合领域,但在处理高度冲突的证据时,可能会出现反直觉的结果.为解决这一问题,本文提出了差异信息量的概念及融合方法.首先,通过信息熵表明证据的相对重要性,采用散度获取证据可信度.然后利用证据可信度优化证据差异度以得到差异信息量,经过计算获取数据的最终权重,并将其作为D-S证据理论中的基本概率分配进行决策.在处理冲突证据、一致证据及不同数量证据等方面的数据融合问题时与其他方法对比,所提方法收敛更快,准确度更高.故障诊断的应用实例表明,所提方法的不确定性更小,优于现存的其他方法. 相似文献
2.
3.
沈洁 《重庆三峡学院学报》2015,(4)
动画片《熊出没》不仅获得了极高的收视率,还获得了“金猴奖”中动画系列片金奖和动画形象金奖两个重量级奖项。该动画片成功的关键在于动画角色的塑造,通过三个主要角色:聪明的熊大、好吃懒做的熊二及顶着大光头的伐木工人,角色设定相对单调,但仍然受到大众的喜爱,原因就在于“创意”独特,符合受众的感知能力,满足了受众群体的视觉需求。在形象塑造上通过故事情节现代化的演绎、夸张动作安排、独特的地方口音和流行化语言风格等富有人性化的艺术表现形式,刻画了三个角色的性格,符合读者的审美期待,实现了虚拟动画和真实受众之间的沟通。 相似文献
4.
Star copolymers have attracted significant interest due to their different characteristics compared with diblock copolymers, including higher critical micelle concentration, lower viscosity, unique spatial shape, or morphologies. Development of synthetic skills such as anionic polymerization and controlled radical polymerization have made it possible to make diverse architectures of polymers. Depending on the molecular architecture of the copolymer, numerous morphologies are possible, for instance, Archimedean tiling patterns and cylindrical microdomains at symmetric volume fraction for miktoarm star copolymers as well as asymmetric lamellar microdomains for star‐shaped copolymers, which have not been reported for linear block copolymers. In this review, we focus on morphologies and microphase separations of miktoarm (AmBn and ABC miktoarm) star copolymers and star‐shaped [(A‐b‐B)n] copolymers with nonlinear architecture. © 2014 Wiley Periodicals, Inc. J. Polym. Sci., Part B: Polym. Phys. 2015 , 53, 1–21 相似文献
5.
《Discrete Mathematics》2021,344(12):112589
Let be the set of positive integers. For a nonempty set A of integers and every integer u, denote by the number of with such that . For a sequence S of positive integers, let be the counting function of S. The set is called a perfect difference set if for every positive integer u. In 2008, Cilleruelo and Nathanson (2008) [4] constructed dense perfect difference sets from dense Sidon sets. In this paper, as a main result, we prove that: let be an increasing function satisfying for any positive integer n, then for every Sidon set B and every function , there exists a set such that for every positive integer u and for all . 相似文献
6.
Synthesis of partially fluorinated poly(arylene ether sulfone) multiblock copolymers bearing perfluorosulfonic functions 下载免费PDF全文
Luca Assumma Cristina Iojoiu Régis Mercier Sandrine Lyonnard Huu Dat Nguyen Emilie Planes 《Journal of polymer science. Part A, Polymer chemistry》2015,53(16):1941-1956
Partially fluorinated poly(arylene ether sulfone) multiblock copolymers bearing perfluorosulfonic functions (ps‐PES‐FPES), with ionic exchange capacity (IEC) ranging between 0.9 and 1.5 meq H+/g, are synthesized by regioselective bromination of partially fluorinated poly(arylene ether sulfone) multiblock copolymers (PES‐FPES), followed by Ullman coupling reaction with lithium 1,1,2,2‐tetrafluoro‐2‐(1,1,2,2‐tetrafluoro‐2‐iodoethoxy)ethanesulfonate. The PES‐FPES are prepared by aromatic nucleophilic substitution reaction by an original approach, that is, “one pot two reactions synthesis.” The chemical structures of polymers are analyzed by 1H and 19F NMR spectroscopy. The resulted ionomers present two distinct glass transitions and α relaxations revealing phase separation between the hydrophilic and the hydrophobic domains. The phase separation is observed at much lower block lengths of ps‐PES‐FPES as compared with the literature. AFM and SANS observations supported the phase separation, the hydrophilic domains are well dispersed but the connectivity to each other depends on the ps‐PES block lengths. The thermomechanical behavior, the water up‐take, and the conductivity of the ps‐PES‐FPES membranes are compared with those of Nafion 117® and randomly functionalized polysulfone (ps‐PES). Conductivities close or higher to those of Nafion 117® are obtained. © 2015 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2015 , 53, 1941–1956 相似文献
7.
A fundamental question in random matrix theory is to quantify the optimal rate of convergence to universal laws. We take up this problem for the Laguerre β ensemble, characterized by the Dyson parameter β, and the Laguerre weight , in the hard edge limit. The latter relates to the eigenvalues in the vicinity of the origin in the scaled variable . Previous work has established the corresponding functional form of various statistical quantities—for example, the distribution of the smallest eigenvalue, provided that . We show, using the theory of multidimensional hypergeometric functions based on Jack polynomials, that with the modified hard edge scaling , the rate of convergence to the limiting distribution is , which is optimal. In the case , general the explicit functional form of the distribution of the smallest eigenvalue at this order can be computed, as it can for and general . An iterative scheme is presented to numerically approximate the functional form for general . 相似文献
8.
Formation of porous polymer morphology by microsyneresis during divinylbenzene polymerization 下载免费PDF全文
Libuše Hanková Ladislav Holub Karel Jeřábek 《Journal of Polymer Science.Polymer Physics》2015,53(11):774-781
This article describes the investigation of the importance of various reaction conditions on microsyneretic pore formation during polymerization of divinylbenzene (DVB) under so‐called “solvothermal” conditions. To induce microsyneretic pore formation, the most important parameter is an unusually high dilution of monomers with a “good” porogen solvating the polymer chains. High dilution and solvation of the growing poly(DVB) chains promote the prolongation of the polymer chains rather than their interconnection by crosslinking. Consequently, when the polymer gel density reaches the point where syneresis starts, the polymer network is geometrically too extensive to be broken up into precipitating entities and, instead, porogen droplets are formed within the continuous polymer gel. The pore geometry created by microsyneresis offers high surface area in wide mesopores and hence, high capacity for supporting functional groups or reactions with much better accessibility than narrow pores between polymer microspheres produced by macrosyneresis in conventional styrenic polymer supports. © 2015 Wiley Periodicals, Inc. J. Polym. Sci., Part B: Polym. Phys. 2015 , 53, 774–781 相似文献
9.
随着SAR成像技术的快速发展,SAR图像覆盖的地域范围与成像精度也在迅速增长,这对SAR图像拼接工作的实时性提出了挑战;文章对SAR图像序列特征进行深入分析,提出了采用基于分割的完全二叉树模型进行SAR图像的并行拼接,并使用MPI点对点通信方式对之进行了不同数量机群规模下的实现;对比实验证明,基于该方法的并行拼接工作比传统并行拼接方法在降低拼接时耗上更加有效,且并行拼接后的完整图像效果良好. 相似文献
10.
Effect of additive length and chemistry on the morphology of blends of conjugated thiophenes and fullerene derivative acceptor molecules 下载免费PDF全文
Small molecule additives have been shown to increase the device efficiency of conjugated polymer (donor) and fullerene derivative (acceptor) based organic solar cells by modifying the morphology of the device active layer. In this paper we conduct a systematic study of how additives affect the donor‐acceptor morphology using molecular dynamics simulations of blends of thiophene‐based oligomers, mimicking poly(3‐dodecylthiophene) (P3DDT) or poly(2,2′:5′,2”‐3,3”‐didocyl‐terthiophene) (PTTT), and fullerene derivatives with additives of varying length and chemical functionalization, mimicking experimentally used additives like methyl ester additives, diiodooctane, and alkanedithiols. We find that functionalization of additives with end groups that are attracted to acceptor molecules are necessary to induce increased donor‐acceptor macrophase separation. In blends where acceptors intercalate between oligomer alkyl side chains, functionalized additives decrease acceptor intercalation. Functionalized additives with shorter alkyl segments increase acceptor macrophase separation more than additives with same chemical functionalization but longer alkyl segments. © 2015 Wiley Periodicals, Inc. J. Polym. Sci., Part B: Polym. Phys. 2015 , 53, 1046–1057 相似文献