A New Bislabdane-type Diterpenoid from Cunninghamia lanceolata

Cunninghmia lanceolata Hook. is a traditional Chinese medicine used for thetreatment of hernia, arthritis and strangury. its chemical constituents have beenexamined]' 2' 3' '. In a previous paper we reported a bislabdane-type diterpenoidlanceolatic acid from the roots of the plant 5. Further chemical studies on this plantled to the isolation of another new bislabdane-type diterpenoid, named lanceolatin(I ).Compound I was obtained as white amorphous powder. mp 232-234 'C, [a]."-24 (c 0. 10, C…     

Two new β-carboline-type alkaloids from Stellaria dichotoma var.lanceolata

Two new β-carboline-type alkaloids,dichotomine K(1) and dichotomine L(2),were isolated from the roots of Chinese medicinal plant Stellaria dichotoma L.var.lanceolata Bge.Structures of 1 and 2 were determined on the basis of chemical and spectroscopic means.     

FeO(OH)@C-Catalyzed Selective Hydrazine Substitution of p-Nitro-Aryl Fluorides and their Application for the Synthesis of Phthalazinones

An efficient hydrazine substitution of p-nitro-aryl fluorides with hydrazine hydrates catalyzed by FeO(OH)@C nanoparticles is described. This hydrazine substitutions of p-nitro-aryl fluorides bearing electron-withdrawing groups proceeded efficiently with high yield and selectivity. Similarly, hydrogenations of p-nitro-aryl fluorides containing electron-donating groups also smoothly proceeded under mild conditions. Furthermore, with these prepared aryl hydrazines, some phthalazinones, interesting as potential structures for pharmaceuticals, have successfully been synthesized in high yields.     

Chemical composition of decomposing stumps in successive rotation of Chinese fir （Cunninghamia lanceolata （Lamb.） Hook.） plantations

Decomposition of stumps in successive rotation of Chinese fir （Cunninghamia lanceolata （Lamb.） Hook.） plantations was studied using a chronosequenee approach. The results showed that decomposition rate constant of Chinese fir stump was 0.02695 as calculated from Olson＇s model. The N content of stump increased during the first two-year decomposition. When the dead stump C/N ratio was 463.2 ± 27.3, the stumps started to release N. The pattern of P release was similar to that for N. However, K content of stumps showed a consistent declining trend over time during the whole decomposition. ^13C nuclear magnetic resonance spectroscopy with cross polarization and magic-angle spinning （^13C CPMAS-NMR） was used to analyse organic carbon （C） components in decomposing stumps. The ^13C CPMAS-NMR spectra of stumps displayed that stump was dominated by cellulose and hemieellulose. The spectra also showed the accumulation of intensity in alkyl C, aromatic C, and earboxyl C spectral regions, which was expected as the labile cellulose and hemieellulose components in O-alkyl C spectral region were selectively decomposed first.     

杉木基因型与环境交互效应的AMMI模型分析

对选自中国南方的１１２个杉木自由授粉家系在八个测试点进行了生长性状的遗传评定。ＡＭＭＩ（加性主效应与复合交互效应）模型分析揭示存在着显著的家系与地点交互效应。根据家系平均ＡＭＭＩ估算和交互第一主分量轴得分对地点所作的聚类分析，以及地点间的遗传相关分析，测试点被划分成四个地点群，有证据表证，就生长性状而言，杉木的育种区早分可能与地理区域尤其是纬度带相重叠。１１２个自由授粉家系依据其交互ＰＣＡ１及平均     

不同碳补贴机制下杉木人工林最优轮伐期和碳汇成本分析

【目的】探讨不同碳补贴机制下最优轮伐期及碳汇成本的变动规律,为提高碳汇供给和降低碳汇成本提供理论依据。【方法】实地调研福建洋口国有林场杉木人工林经营和营林实践,推导不同碳补贴情境下杉木最优轮伐期和碳汇成本模型,分析立地条件、碳价格、贴现率对最优轮伐期和碳汇成本的影响。【结果】理想情境下,贴现率由2%上涨至7%时,优、中和劣等立地的碳汇成本分别下降了31.42%、32.03%和33.15%,最优轮伐期均缩短4 a。碳价格由20元/t增加至350元/t时,优、中和劣等立地碳汇成本上涨了19.24、19.43和19.38倍,最优轮伐期分别延长了8、9和10 a。年给付情境下,贴现率由2%上涨至7%时,优、中和劣等立地的碳汇成本分别下降了70.35%、70.66%和71.14%,最优轮伐期均缩短4 a。碳价格由20元/t增加至350元/t时,优、中和劣等立地的碳汇成本上涨了15.79、15.82和16.50倍,中等立地和优等立地最优轮伐期均延长1 a,劣等立地最优轮伐期维持不变。【结论】两种碳补贴情境下,碳汇成本和最优轮伐期均与贴现率负相关,与碳价格正相关。在理想情境下,中等立地碳汇成本对碳价格变动的敏感性最强,但在年给付情境下,劣等立地碳汇成本对碳价格变动敏感性最强。总之,在研究区,理想情境更有利于发挥森林生态功能,实现森林生态效益。     

七溪岭林场刨花楠与杉木混交造林技术及效果分析

通过七溪岭林场刨花楠与杉木大面积混交造林实验，总结培育刨花楠混交林的技术和方法；根据刨花楠与杉木混交造林的成果与效果分析，提出七溪岭林场改善林分结构的方法和途径。     

Separation and purification of quinolyridine alkaloids from seeds of Thermopsis lanceolata R. Br. by conventional and pH-zone-refining counter-current chromatography

In this work, the preparative separation of quinolyridine alkaloids from seeds of T. lanceolata by conventional and pH-zone-refining counter-current chromatography. Traditional counter-current chromatography separation was performed by a flow-rate changing strategy with a solvent system of ethyl acetate-n-butanol-water (1:9:10, v/v) and 200 mg sample loading. Meanwhile, the pH-zone-refining mode was adopted for separating 2.0 g crude alkaloid extracts with the chloroform-methanol-water (4:3:3, v/v) solvent system using the stationary and mobile phases of 40 mM hydrochloric acid and 10 mM triethylamine. Finally, six compounds, including N-formylcytisine (two conformers) ( 1 ), N-acetycytisine (two conformers) ( 2 ), (-)-cytisine ( 3 ), 13-β-hydroxylthermopsine ( 4 ), N-methylcytisine ( 5 ), and thermopsine ( 6 ) were successfully obtained in the two counter-current chromatography modes with the purities over 96.5%. Moreover, we adopted nuclear magnetic resonance and mass spectrometry for structural characterization. Based on the obtained findings, the pH-zone-refining mode was the efficient method to separate quinolyridine alkaloids relative to the traditional mode.     

邻株低磷竞争处理对杉木幼苗生长的影响

以南方林区广泛种植杉木无性系为研究对象,利用室内沙培模拟装置,设置缺磷(0 mg/kg KH2PO4)、低磷(6 mg/kg KH2PO4)和正常供磷(12 mg/kg KH2PO4)3个供磷水平,构建邻株磷竞争环境.结果表明:邻株低磷竞争处理可明显促进杉木苗高生长,但竞争条件下,缺磷处理抑制杉木苗高生长.不同邻株磷竞争处理条件下杉木地径生长差异未达显著水平.在邻株低磷竞争处理条件下杉木根系长度、表面积、直径、体积等形态指标增量最大.